NAPHTHO[1,2,3,4-GHI]PERYLENE synthesis
8synthesis methods
- Product Name:NAPHTHO[1,2,3,4-GHI]PERYLENE
- CAS Number:190-84-1
- Molecular formula:C26H14
- Molecular Weight:326.39
Yield:190-84-1 77%
Reaction Conditions:
Stage #1: anthranilic acidwith para-dodecylbenzenesulfonic acid;isopentyl nitrite in ethyl acetate at 25; for 1 h;Diels-Alder Cycloaddition;
Stage #2: PERYLENEwith potassium fluoride;18-crown-6 ether in toluene at 100; for 2 h;Diels-Alder Cycloaddition;Solvent;
References:
Pavlyuk;Gundala;Kovalev;Kopchuk;Krinochkin;Budeev;Zyryanov;Venkatapuram;Rusinov;Chupakhin [Russian Journal of Organic Chemistry,2019,vol. 55,# 3,p. 409 - 411][Zh. Org. Khim.,2019,vol. 55,# 3,p. 477 - 480,4]
![Naphtho[1,2-g]chrysene](/CAS/20210305/GIF/191-67-3.gif)
![DIBENZO[E,GHI]PERYLENE](/CAS/GIF/190-95-4.gif)
