(S)-12-hydroxyoctadecanoic acid synthesis
- Product Name:(S)-12-hydroxyoctadecanoic acid
- CAS Number:18417-00-0
- Molecular formula:C18H36O3
- Molecular Weight:300.4767
1033405-13-8
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18417-00-0
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Yield:18417-00-0 81%
Reaction Conditions:
Stage #1: (S)-nonadec-18-en-7-olwith osmium(VIII) oxide in N,N-dimethyl-formamide;tert-butyl alcohol at 20; for 0.0833333 h;
Stage #2: with oxone in N,N-dimethyl-formamide;tert-butyl alcohol at 20;optical yield given as %ee;chemoselective reaction;
References:
Habel, Andreas;Boland, Wilhelm [Organic and Biomolecular Chemistry,2008,vol. 6,# 9,p. 1601 - 1604] Location in patent:supporting information; experimental part
6114-39-2
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18417-00-0
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