S-N-PROPYL THIOACETATE synthesis
- Product Name:S-N-PROPYL THIOACETATE
- CAS Number:2307-10-0
- Molecular formula:C5H10OS
- Molecular Weight:118.2
107-03-9
253 suppliers
$14.00/25mL
75-36-5
576 suppliers
$17.92/100G
2307-10-0
153 suppliers
$23.00/5g
Yield: 82%
Reaction Conditions:
at 60; for 4 h;
Steps:
Synthesis of S-Esters of Thiocarboxylic Acids
General procedure: A mixture of an aliphatic or aromatic thiol (0.1 mol) and a carboxylic acid chloride (0.2 mol) was heated for 4 h at 60°C; after cooling, it was diluted with 60 mL of benzene, washed with a saturated solution of NaHCO3 (4 × 30 mL), and dried over MgSO4. The desired products were isolated by the fractionation of the residue under atmospheric pressure (compounds 1 and 2) or in a vacuum (compounds 3-19). S-n-propyl thioacetate (1): yield 9.7 g (82%), bp136°C, 1.4556, 0.9793. IR spectrum (thin film,ν, cm-1): 1695 (C=O). 1H NMR spectrum (CDCl3, δ,ppm): 0.92 (t, 3J 6.9 Hz, 3H, Me), 1.52 (m, 2H, CH2),2.30 (s, 3H, Me), 2.87 (t, 3J 6.9 Hz, CH2S). 13C NMRspectrum (CDCl3, δ, ppm): 13.3 (Me), 22.7 (CH2),30.5 (Me), 30.6 (CH2S), 194.0 (C=O).
References:
Aliev;Belovezhets;Oparina [Petroleum Chemistry,2019,vol. 59,# 1,p. 99 - 105][Neftekhimiya,2019,vol. 59,# 1,p. 91 - 97,7]
107-03-9
253 suppliers
$14.00/25mL
631-61-8
839 suppliers
$11.19/100G
2307-10-0
153 suppliers
$23.00/5g
506-96-7
322 suppliers
$22.39/25G
106-97-8
116 suppliers
$36.00/1mL
2307-10-0
153 suppliers
$23.00/5g
928-47-2
37 suppliers
$60.00/500mg
2432-32-8
0 suppliers
inquiry
507-02-8
59 suppliers
$144.00/1g
![Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy-](/CAS/20210305/GIF/1000210-73-0.gif)
1000210-73-0
0 suppliers
inquiry
2307-10-0
153 suppliers
$23.00/5g
994-49-0
116 suppliers
$16.00/1g