Tetravinylsilane synthesis
- Product Name:Tetravinylsilane
- CAS Number:1112-55-6
- Molecular formula:C8H12Si
- Molecular Weight:136.27
75-01-4
142 suppliers
$19.69/1mL
75-94-5
203 suppliers
$21.00/25g
1112-55-6
179 suppliers
$106.00/5g
Yield:1112-55-6 76.5%
Reaction Conditions:
Stage #1: chloroethylenewith magnesium in tetrahydrofuran at 35 - 45; for 7.5 h;
Stage #2: trichlorovinylsilane in tetrahydrofuran at 20; for 4 h;Reflux;
Steps:
1 Example 1
Stirrer, condenser, thermometer, 2L 4-neck flask,Attaching a gas blowing tube, magnesium 76.5g(3.15 mol) and THF 1008 ml were charged,Blowing vinyl chloride in 6.5 hours while controlling the temperature to 35 to 45° C., and aging at the same temperature for 1 hour, magnesium disappeared,A THF solution of vinylmagnesium chloride was obtained.The blown amount of vinyl chloride was 412.5 g.161.5 g (1.0 mol) of vinyltrichlorosilane was added dropwise to the obtained THF solution of vinylmagnesium chloride at 20 to 50° C. over 3 hours, and then the temperature was raised to the reflux temperature and the mixture was aged for 1 hour. After cooling the obtained reaction solution to room temperature, 550 g of water was added to produce a by-product.The magnesium salt was dissolved and removed by liquid separation. The obtained organic layer was distilled under reduced pressure to obtain 104.3 g (0.765 mol) of tetravinylsilane. The yield was 76.5%.
References:
JP2020/79219,2020,A Location in patent:Paragraph 0022
75-01-4
142 suppliers
$19.69/1mL
1112-55-6
179 suppliers
$106.00/5g
3536-96-7
201 suppliers
$67.00/100ml
1112-55-6
179 suppliers
$106.00/5g
3536-96-7
201 suppliers
$67.00/100ml
2372-31-8
39 suppliers
inquiry
1112-55-6
179 suppliers
$106.00/5g
2372-31-8
39 suppliers
inquiry
3536-96-7
201 suppliers
$67.00/100ml
1112-55-6
179 suppliers
$106.00/5g