Tris(2-chloroethyl) phosphate synthesis
- Product Name:Tris(2-chloroethyl) phosphate
- CAS Number:115-96-8
- Molecular formula:C6H12Cl3O4P
- Molecular Weight:285.49
75-21-8
242 suppliers
$33.29/crm44609
115-96-8
329 suppliers
$19.00/10g
Yield:115-96-8 99.2%
Reaction Conditions:
with trichlorophosphate at 10; for 2 h;Autoclave;Reflux;
Steps:
General procedure: The catalyst and POCl3 (0.1 mol) was added into the autoclave. Then epoxypropane (0.33 mol) was dropped in a way that the temperature did not increase more than 10 °C. Then the resulting mixture was stirred for 2 h at reflux temperature. After the stirring had been stopped, the reaction mixture was evaporated under reduced pressure to remove excessive epoxypropane. The catalyst was filtered and the product was illustrated by 1H NMR and IR. The IR spectra was recorded on a Nicolete spectrometer and expressed in cm-1 (KBr). 1H NMR spectra was recorded with a Varian XL-400 spectrometer.
References:
Zhi, Hui Zhen;Shi, Hong Li;Hu, Yun;Xia, Ke Dan;Zhang, Peng;Yang, Jin Fei [Chinese Chemical Letters,2012,vol. 23,# 11,p. 1217 - 1220,4]
107-07-3
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$18.30/50ml
115-96-8
329 suppliers
$19.00/10g
140-08-9
97 suppliers
$47.00/5mL
115-96-8
329 suppliers
$19.00/10g
74-85-1
115 suppliers
$79.00/11l
115-96-8
329 suppliers
$19.00/10g