2,5-Dimethylhexan-2,5-diol
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- CAS-Nr.
- 110-03-2
- Bezeichnung:
- 2,5-Dimethylhexan-2,5-diol
- Englisch Name:
- 2,5-Dimethyl-2,5-hexanediol
- Synonyma:
- 2,5-DIMETHYLHEXANE-2,5-DIOL;2,5-Hexanediol, 2,5-dimethyl-;1,1,4,4-Tetramethyl-1,4-butanediol;nsc5595;ai3-20685;5-hexanediol;-2,5-hexanedioL;dimethylhexanediol;DiMethyl-2,5-hexan;2,5-Dimethyl-2,5-hex
- CBNumber:
- CB3335426
- Summenformel:
- C8H18O2
- Molgewicht:
- 146.23
- MOL-Datei:
- 110-03-2.mol
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2,5-Dimethylhexan-2,5-diol Eigenschaften
- Schmelzpunkt:
- 86-90 °C (lit.)
- Siedepunkt:
- 214-215 °C (lit.)
- Dichte
- 0,898 g/cm3
- Dampfdruck
- 0.18Pa at 20℃
- Brechungsindex
- 1.4429 (estimate)
- Flammpunkt:
- 126 °C
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- pka
- 15.07±0.29(Predicted)
- Aggregatzustand
- Crystalline Flakes
- Farbe
- White
- Geruch (Odor)
- mild camphor
- Wasserl?slichkeit
- SOLUBLE
- BRN
- 1361437
- Henry's Law Constant
- 1.4×101 mol/(m3Pa) at 25℃, Zhang et al. (2010)
- InChI
- 1S/C8H18O2/c1-7(2,9)5-6-8(3,4)10/h9-10H,5-6H2,1-4H3
- InChIKey
- ZWNMRZQYWRLGMM-UHFFFAOYSA-N
- SMILES
- CC(C)(O)CCC(C)(C)O
- LogP
- 0.21 at 23℃
- CAS Datenbank
- 110-03-2(CAS DataBase Reference)
- NIST chemische Informationen
- 2,5-Hexanediol, 2,5-dimethyl-(110-03-2)
- EPA chemische Informationen
- 2,5-Hexanediol, 2,5-dimethyl- (110-03-2)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
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P264, P280, P305+P351+P338,P337+P313P |
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| Sicherheit |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
| P337+P313 |
Bei anhaltender Augenreizung: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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2,5-Dimethylhexan-2,5-diol Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
Colorless or white crystalline flakes. M.P. 93°C.
B.P. 213°C. Soluble in water (20°C 140g/L), miscible with alcohol and
most oils. Faint, camphorlike odor.
Verwenden
2,5-Dimethyl-2,5-hexanediol was used in the synthesis of six- and seven-membered heterocyclic boron compounds containing intramolecular N-B bond.
synthetische
The raw materials 2,5-Dimethyl-3-hexyne-2,5-diol (37.4 g, 263 mmol), ethyl acetate (60 mL), and Pd/C catalyst (0.285 g, 2.63 mmol, 1 mol %) were added to an autoclave. The hydrogen gas was slowly added to 10 bar. When the hydrogenation reaction was performed for 12 hours and then removed the hydrogen gas. Finally, 2,5-Dimethyl-2,5-hexanediol is obtained by purification.
Allgemeine Beschreibung
2,5-Dimethyl-2,5-hexanediol on heteropoly acid catalyzed dehydration yields cyclic ethers via stereospecific intramolecular S
N2 mechanism. It reacts with nitriles in concentrated sulfuric acid to yield Δ
1-pyrrolines.
l?uterung methode
Purify the diol by fractional crystallisation. Then the diol is dissolved in hot acetone, treated with activated charcoal, and filtered while hot. The solution is cooled and the diol is filtered off and washed well with cold acetone. The crystallisation process ia repeated several times, and the crystals are dried under a vacuum in a freeze-drying apparatus [Goates et al. J Chem Soc, Faraday Trans 1 78 3045 1982]. [Beilstein 1 IV 2600.]
2,5-Dimethylhexan-2,5-diol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Bexarotene
1,2,3,4-Tetrahydro-1,1,4,4-tetramethylnaphthalin
2,5-Dichlor-2,5-dimethylhexan
1,2,3,4-Tetrahydro-1,1,4,4,6-pentamethylnaphthalin
Naphthalene,6-chloro-1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-
2,5-Dimethylhexan-2,5-diol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 435)Lieferanten
110-03-2(2,5-Dimethylhexan-2,5-diol)Verwandte Suche:
- 2,5-dimethyl-5-hexanediol
- 5-Hexanediol,2,5-dimethyl-2
- DiMethyl-2,5-hexan
- 2,5-Dimethyl-2,5-hex
- 2,5-DiMethyl-2,5-hexanediol, 99% 250GR
- 2,5-Dimethyl-2,5-hexanediol,99%
- 2,5-DiMethyl-2,5-hexanediol, 99.5%
- 2, 5 - diMethyl - 2, 5 - diol
- 2,5-Dimethyl-2,5-hexanediol 97%
- ai3-20685
- dimethylhexanediol
- nsc5595
- 2,5-DIHYDROXY-2,5-DIMETHYLHEXANE
- 2,5-DIMETHYLHEXAN-2,5-DIOL
- 2,5-DIMETHYL-2,5-HEXANDIOL
- 2,5-DIMETHYL-2,5-HEXANEDIOL
- 2,5-DIMETHYLHEXANEDIOL
- 2,5-DIMETHYLOHEXANEDIOL
- 2，5-dimethyl-2，5-hexadiol
- 5-hexanediol
- 7,12-dimethylbenzo[a]anthracene-5,6-dione
- 2,5-Dimethyl-2,5-hexanediol >
- 2,5-Dimethyl-2,5-hexanediol Basic information
- -2,5-hexanedioL
- 1,1,4,4-Tetramethyl-1,4-butanediol
- 2,5-Dimethyl-2,5-hexanediol, ≥ 99.0%
- 2,5-DIMETHYLHEXANE-2,5-DIOL
- 2,5-Hexanediol, 2,5-dimethyl-
- 110-03-2
- 1864-01-0
- CH3CCH3OHCH2CH2CCH3OHCH3
- CH32COHCH2CH2COHCH32
- Building Blocks
- Organic Building Blocks
- Polyols
- Oxygen Compounds
- Organic Building Blocks
- Oxygen Compounds
- Polyols
- Building Blocks
- Chemical Synthesis
- Organic Building Blocks
- Oxygen Compounds
- bc0001
