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N,N,N',N'-Tetramethyl-4,4-methylendianilin

4,4'-Methylenebis(N,N-dimethylaniline) Struktur
101-61-1
CAS-Nr.
101-61-1
Bezeichnung:
N,N,N',N'-Tetramethyl-4,4-methylendianilin
Englisch Name:
4,4'-Methylenebis(N,N-dimethylaniline)
Synonyma:
michler’sbase;Michler's base;N,N,N',N'-TETRAMETHYL-4,4'-METHYLENEDIANILINE;NCI-C01990;TETRA BASE;Methane Bas;ARNOLDS BASE;METHANE BASE;methylenebase;bazemichlerova
CBNumber:
CB4327020
Summenformel:
C17H22N2
Molgewicht:
254.37
MOL-Datei:
101-61-1.mol

N,N,N',N'-Tetramethyl-4,4-methylendianilin Eigenschaften

Schmelzpunkt:
88-89 °C(lit.)
Siedepunkt:
390 °C
Dichte
1.0344 (rough estimate)
Brechungsindex
1.5794 (estimate)
Flammpunkt:
178 °C
storage temp. 
Sealed in dry,Room Temperature
pka
5.57±0.12(Predicted)
Aggregatzustand
Crystalline Powder, Crystals and/or Chunks
Farbe
Off-white or light gray or beige-brown
Wasserl?slichkeit
Insoluble
Merck 
14,6176
BRN 
479956
Henry's Law Constant
8.2×101 mol/(m3Pa) at 25℃, HSDB (2015)
Stabilit?t:
Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, active metals, oxides, chlorates, halogenated compounds, iron chloride, nitro acompounds, peroxides, strong ammonia solution, sulfides, vinyl polymers.
Major Application
diagnostic assay manufacturing
hematology
histology
InChI
1S/C17H22N2/c1-18(2)16-9-5-14(6-10-16)13-15-7-11-17(12-8-15)19(3)4/h5-12H,13H2,1-4H3
InChIKey
JNRLEMMIVRBKJE-UHFFFAOYSA-N
SMILES
CN(C)c1ccc(Cc2ccc(cc2)N(C)C)cc1
CAS Datenbank
101-61-1(CAS DataBase Reference)
IARC
2B (Vol. 27, Sup 7, 99) 2010
NIST chemische Informationen
Benzenamine, 4,4'-methylenebis[N,N-dimethyl-(101-61-1)
EPA chemische Informationen
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T,N,Xi
R-S?tze: 45-50/53
S-S?tze: 53-45-60-61
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS-Nr. BY5250000
Hazard Note  Harmful/Irritant
TSCA  TSCA listed
HazardClass  6.1(b)
PackingGroup  III
HS Code  29215990
Speicherklasse 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Carc. 1B
Giftige Stoffe Daten 101-61-1(Hazardous Substances Data)
Bildanzeige (GHS) Health Hazard (GHS08)Environment (GHS09)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H350 Kann Krebs verursachen. Karzinogenit?t Kategorie 1A Achtung
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung P273, P391, P501
Sicherheit
P202 Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P308+P313 BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen.
P391 Verschüttete Mengen aufnehmen.
P405 Unter Verschluss aufbewahren.

N,N,N',N'-Tetramethyl-4,4-methylendianilin Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R45:Kann Krebs erzeugen.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.

S-S?tze Betriebsanweisung:

S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Chemische Eigenschaften

yellow to tan crystals

Verwenden

4,4'-Methylenebis(N,N-dimethylaniline)is used as a chemical intermediate in the manufacture of dyes and for its hydrochloric salt and is also used as an analytical reagent in the determination of lead.

Allgemeine Beschreibung

Yellowish glistening leaflets or plates or tan crystals. Weak odor. Sublimes without decomposition.

Air & Water Reaktionen

Insoluble in water.

Reaktivit?t anzeigen

4,4'-Methylenebis(N,N-dimethylaniline) is incompatible with acids, acid chlorides, acid anhydrides and oxidizing agents. 4,4'-Methylenebis(N,N-dimethylaniline) is also incompatible with active metals, potassium, oxides, chlorates, halogenated compounds, iron chloride, nitro compounds, peroxides, strong ammonia solutions, sulfides and vinyl polymers .

Brandgefahr

4,4'-Methylenebis(N,N-dimethylaniline) is combustible.

Sicherheitsprofil

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. A flammable liquid. When heated to decomposition it emits toxic fumes of NOx.

m?gliche Exposition

4,40 -methylenebis(N,N-dimethyl) benzenamine is used as an intermediate in dye manufacture and as an analytical reagent in the determination of lead.

Carcinogenicity

4,4′-Methylenebis(N,N-dimethyl)benzenamine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Versand/Shipping

UN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

l?uterung methode

Crystallise the base from EtOH (2mL/g) or 95% EtOH (ca 12mL/g). It sublimes on heating. [Beilstein 13 IV 390.]

Inkompatibilit?ten

Strong acids, oxidizers, acid chlorides; acid anhydrides.

N,N,N',N'-Tetramethyl-4,4-methylendianilin Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


N,N,N',N'-Tetramethyl-4,4-methylendianilin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 223)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Chuanghai Biotechnology Co., Ltd
+8615350571055
Sibel@chuanghaibio.com China 8738 58
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29812 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49979 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763
sales@tnjchem.com China 34563 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739
info@dycnchem.com China 52704 58
Shaanxi Didu New Materials Co. Ltd
+86-86-17392712697 +8617792793228
1069@dideu.com China 8662 58
Hebei Fengjia New Material Co., Ltd
+86-0311-87836622 +86-18712993135
sales01@tairunfaz.com China 8051 58
PT CHEM GROUP LIMITED
+86-85511178;
peter68@ptchemgroup.com China 35425 58
GIHI CHEMICALS CO.,LIMITED
+86-571-86217390; +8618058761490
info@gihichemicals.com China 49962 58
HANGZHOU LEAP CHEM CO., LTD.
+86-571-87711850
market18@leapchem.com China 43333 58

101-61-1(N,N,N',N'-Tetramethyl-4,4-methylendianilin)Verwandte Suche:


  • Aniline, 4,4'-methylenebis[N,N-dimethyl-
  • Baze michlerova
  • bazemichlerova
  • bazemichlerova(czech)
  • Benzenamine, 4,4'-methylenebis*N,N-dimethyl-
  • bis(4-(n,n-dimethylamino)phenyl)methane
  • bis(p-(dimethylamino)phenyl)-methan
  • bis(p-(n,n-dimethylamino)phenyl)methane
  • bis(p-dimethylamino)diphenylmethane
  • Bis[4-(N,N-dimethylamino)phenyl]methane
  • Bis[p-(N,N-dimethylamino)phenyl]methane
  • Diphenylmethane, tetramethyldiamino-
  • Methane base Michler's hydride
  • Methane, bis(4,4'-dimethylaminophenyl)-
  • Methane, bis(p-(dimethylamino)phenyl)-
  • Methanediamine, tetramethyl-N,N'-diphenyl-
  • Methylene base
  • methylenebase
  • methylenebis(n,n-dimethylaniline)
  • michler’sketone,reduced
  • michler’smethane
  • Michler's methane
  • N-(4-[4-(Dimethylamino)benzyl]phenyl)-N,N-dimethylamine
  • N,N,N',N'-Tetramethyl-p,p'-diaminodiphenylmethane
  • N,N,N’,N’-Tetramethyl-4,4’-dia
  • n,n,n’,n’-tetramethyl-p,p’-diaminodiphenylmethane
  • n,n,n’n’-tetramethyl-p,p’-diaminodiphenylmethane
  • 4,4'-Tetramethyldia
  • n,n’-tetramethyldiaminodiphenylmethane
  • N,N'-Tetramethyldiaminodiphenylmethane
  • NCI-C01990
  • p,p’-bis(dimethylamino)diphenylmethane
  • p,p’-bis(n,n-dimethylaminophenyl)methane
  • p,p'-Bis(dimethylamino)diphenylmethane
  • p,p'-Bis(N,N-dimethylaminophenyl)methane
  • p,p-Dimethylaminodiphenylmethane
  • Reduced michler'S ketone
  • reducedmichler’sketone
  • tetramethyldiamino-diphenylmethan
  • 4,4'-Bis(diMethylaMinophenyl)Metha
  • Methane Base 4,4'-Methylenebis(N,N-dimethylaniline) Tetra Base 4,4'-Tetramethyldiaminodiphenylmethane
  • 4,4’-methylenebis(n,n-dimethyl)-benzenamine
  • 4,4’-methylenebis(n,n-dimethyl-anilin
  • 4,4’-methylenebis(n,n-dimethyl-benzenamin
  • 4,4’-methylenebis(N,N-dimethyl-Benzenamine
  • 4,4'-(Dimethylamino)diphenylmethane
  • 4,4’-(dimethylamino)diphenylmethane
  • 4,4’-methylenebis(n,n-dimethyl)benzenamine
  • Bis[4-(dimethylamino)phenyl]methane 4,4'-Methylenebis(N,N-dimethylaniline)
  • N,N,N′,N′-Tetramethyl-4,4′-methylenedianiline,4,4′-Methylenebis-N,N-dimethylaniline, Arnolds base, N,N,N′,N′-Tetramethyl-4,4′-diaminodiphenylmethane
  • 4,4′-Methylenebis(N,N-dimethylaniline),N,N,N′,N′-Tetramethyl-4,4′-diaminodiphenylmethane, N,N,N′,N′-Tetramethyl-4,4′-methylenedianiline, Arnolds base
  • 4,4′-Methylenebis(N
  • Methane Bas
  • N,N,N′,N′-Tetramethyl-4,4′-methylenedianiline N,N,N′,N'-Tetramethyl-4,4'-diaminodiphenylmethane Arnolds base 4,4'-Tetramethyldiaminodiphenyl methane Bis[4-(dimethylamino)phenyl]methane 4,4'-Methylenebis(N,N-dimethylaniline) Methane Base Tetra
  • tetramethyl-n,n’-diphenyl-methanediamin
  • Methylene bis(N,N'-dimethyl)aniline, 4,4'-? Michler's Base
  • 4,4'-bis(N,N-dimethyl)aminodiphenylmethane
  • 4,4'-Methylenebis(N,N-dimethylaniline)~N,N,N',N'-Tetramethyl-4,4'-diaminodiphenylmethane
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