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?ther >2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin
2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin
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- CAS-Nr.
- 14098-44-3
- Bezeichnung:
- 2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin
- Englisch Name:
- Benzo-15-crown-5
- Synonyma:
- 2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine;denzo15c5;benzo15c5;BENZO-15-CROWN-5;Benzene-15-Crown-5;Benzo-15-crown-5,99%;Monobenzo-15-crown-5;Benzo-15-crown-5,97%;2,3-Benzo-15-crown-5;Benzo-15-crown-5,>98%
- CBNumber:
- CB5223772
- Summenformel:
- C14H20O5
- Molgewicht:
- 268.31
- MOL-Datei:
- 14098-44-3.mol
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2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Eigenschaften
- Schmelzpunkt:
- 78-80 °C (lit.)
- Siedepunkt:
- 371.47°C (rough estimate)
- Dichte
- 1.1846 (rough estimate)
- Brechungsindex
- 1.4825 (estimate)
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Powder or Flakes
- Farbe
- Almost white to light gray
- Wasserl?slichkeit
- partially soluble
- Sensitive
- Hygroscopic
- BRN
- 1624106
- InChI
- InChI=1S/C14H20O5/c1-2-4-14-13(3-1)18-11-9-16-7-5-15-6-8-17-10-12-19-14/h1-4H,5-12H2
- InChIKey
- DSFHXKRFDFROER-UHFFFAOYSA-N
- SMILES
- O1C2=CC=CC=C2OCCOCCOCCOCC1
- CAS Datenbank
- 14098-44-3(CAS DataBase Reference)
- NIST chemische Informationen
- Bis(1,4,7,10,13-benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-)(14098-44-3)
2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
ALMOST WHITE TO LIGHT GREY POWDER OR FLAKES
Verwenden
Benzo-15-crown-5 is used in synthetic chemistry. It plays a major role and involved in complexation through ether oxygen. It is used in phase-transfer catalyst system. It is involved in 'Host-Guest' chemistry to identify the move of essential elements in the body. It can play the part of very complicated biological reactions such as enzyme functions, which finds application in the development of new pharmaceuticals.
Application
Benzo-15-crown-5 can be used for sol-gel material extraction to separate lithium isotopes, for making static detection sensors for formic acid gases, and as metal ion complexing agent and phase transfer reagent.
synthetische
synthesis of Benzo-15-crown-5: benzo-15-crown-5 can be produced using Williamson synthesis reaction, featured by interaction between catechol (orto-dihydroxybenzene) and tetraethylene glycol dichloride (1,10-dichloro-3,6,9-trioxadecane) over sodium hydroxide in the n-butanol media (30-h inertatmosphere boiling). The yield of benzo-15-crown-5 produced by this method is 62%, with the basic substance's mass fraction of 95%.
Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives
2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Tetrabutylammoniumiodid
GLYCOFUROL
Tosylchlorid
Tetrahydrofuran
1,2-Dihydroxybenzol
Natriumhydroxid
Ethane, 1,1'-oxybis[2-(2-iodoethoxy)-
O,O'-BIS(2-HYDROXYETHOXY)BENZENE
2,2'-(2,2'-(1,2-phenylenebis(oxy))bis(ethane-2,1-diyl))bis(oxy)diethanol
(1,2-phenylenebis(oxy))bis(ethane-2,1-diyl)bis(4-methylbenzenesulfonate)
4'-BROMOBENZO-15-CROWN 5-ETHER
4'-FORMYLBENZO-15-CROWN 5-ETHER
Ethane,1,1'-Oxybis〔2-(2-bromoethoxy)-
Pentaethylene Glycol Dimethanesulfonate
Tetraethylene glycol di-p-tosylate
DIETHYLENE GLYCOL BIS(P-TOLUENESULFONATE)
Downstream Produkte
2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 273)Lieferanten
14098-44-3(2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin)Verwandte Suche:
Benzothiazol
Benzotriazol (in atembarer Form)
1,4,10,13-Pentaoxacyclopentadecan
1,4,7,10-Tetraoxacyclododecan
Benzimidazol
Benzo[b]thiophen
Benzothiazol-2-thiol
Benzoesure, C12-15-Alkylester
2-Benzothienylboronic acid
Pentadec-1-en
2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin
- Benzo-15-crown-5, 99% 2.5GR
- CROWN ETHER/BENZO-15-CROWN-5 FOR SYNTHES
- 2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-15,17,19-triene
- 1,2-[Oxybis(ethyleneoxyethyleneoxy)]benzene
- 2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene
- 6,7,9,10,12,13,15,16-Octahydro-5,8,11,14,17-pentaoxa-5H-benzocyclopentadecene
- Benzo-15-crown-5,99%
- denzo15c5
- Monobenzo-15-crown-5
- 2,3-BENZO-1,4,7,10,13-PENTAOXACYCLOPENTADEC-2-ENE
- 2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLOPENTADECIN
- 1,4,7,10,13-PENTAOXA(13)ORTHOCYCLOPHANE
- BENZO-15-CROWN-5
- BENZO-15-CROWN 5-ETHER
- CROWN ETHER/BENZO-15-CROWN-5
- Benzo-15-crown-5,97%
- Crown ether/Benzo-15-crown-5 for synthesis
- 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-
- 2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine
- 2,3-benzo-1,4,7,10,13-pentaoxacyclopentadecane
- 2,3-Benzo-15-crown-5
- 4,7,10,13-Benzopentaoxacyclopentadecin,2,3,5,6,8,9,11,12-octahydro-1
- 7,10,13-benzopentaoxacyclopentadecin,2,3,5,6,8,9,11,12-octahydro-4
- Benzo[6]1,4,7,10,13-pentaoxacyclopentadecane
- benzo15c5
- Benzo-15-crown 5-Ether >
- Benzo-15-crown-5, 98%, reagent grade
- Benzo-15-crown-5,>98%
- 14098-44-3 Benzo-15-crown-5
- 2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(19),15,17-triene
- 2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine
- Benzo -15- crown ether -5
- Benzo-15-crown-5(2,3,5,6,8,9,11,12-Octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin)
- Benzene-15-Crown-5
- benzenebenzo-15-ether-5
- 14098-44-3
- C14H20O5
- Synthetic Reagents
- Chelation/Complexation Compounds
- Crown Ethers
- Macrocycles for Host-Guest Chemistry
- crown ether
- Crown Ethers
- Functional Materials
- Macrocycles for Host-Guest Chemistry
- Chelation/Complexation Compounds
- Crown Ethers
- Synthetic Reagents
