Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium
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- CAS-Nr.
- 12257-42-0
- Bezeichnung:
- Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium
- Englisch Name:
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
- Synonyma:
- [Rh(nbd)Cl]2;Chiralyst P461;bis[(2,3,5,6-B7;-chlorodirhodium;4-norbornadiene)dirhodium(I);Dichloro(norbornadiene)dirhodium;NORBORNADIENE RHODIUM(1) CHLORIDE;Chloronorbornadiene rhodium dimer;Bis[chloro(norbornadiene)rhodium];BIS(NORBORNADIENE-MU-CHLORORHODIUM)
- CBNumber:
- CB5697449
- Summenformel:
- C14H16Cl2Rh28*
- Molgewicht:
- 460.99
- MOL-Datei:
- 12257-42-0.mol
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Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium Eigenschaften
- Schmelzpunkt:
- 239-241°C (dec.)
- storage temp.
- 2-8°C
- L?slichkeit
- sol chloroform and benzene; insol ether and light petroleum
- Aggregatzustand
- Powder
- Farbe
- yellow to orange
- Wasserl?slichkeit
- insoluble in water
- Expositionsgrenzwerte
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
- InChI
- InChI=1/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;
- InChIKey
- RXDWVIOULPVOEO-SEGRDSFWNA-L
- SMILES
- [C@@]12([H])[CH][CH][C@]([CH][CH]1)([H])C2.[C@@]12([H])[CH][CH][C@@]([H])([CH][CH]1)C2.Cl[Rh].Cl[Rh] |&1:0,4,9,13,r,^1:2,3,5,6,11,12,15,16|
Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
mustard yellow crystals
Verwenden
Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization
synthetische
Bis(bicyclo[2.2.1]hepta-2,5- diene)dichlorodirhodium is prepared by reacting rhodium(III) Chloride and bicyclo[2.2.1]hepta-2,5-diene in aq ethanol, when shaken for 2 days, give a yellow deposit.
l?uterung methode
It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.]
Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 190)Lieferanten
12257-42-0(Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium)Verwandte Suche:
Tris(triphenylphosphin)rhodium(I)chlorid
Tris(pentan-2,4-dionato-O,O')ruthenium
Dichlortris(triphenylphosphin)ruthenium
Tetrakis[μ-(acetato-O:O')]dirhodium
Tris(pentan-2,4-dionato-O,O')rhodium
Rhodium
exo-Bicyclo[2.2.1]heptan-2-ol
8,9,10-Trinorborna-2,5-dien
Bis[(2,3,5,6-?)-bicyclo[2.2.1]hepta-2,5-dien]di-μ-chlorodirhodium
- NORBORNADIENE RHODIUM(1) CHLORIDE
- NORBORNADIENE RHODIUM(I) CHLORIDE DIMER
- RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER
- Chloronorbornadienerhodium(I)dimer,99%
- di-ae-chlorobis(norbornadiene) dirhodium(i)
- bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium
- BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I)
- Chloro(norbornadiene)rhodium(I), dimer, 99.9%
- Di-μ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
- 4-norbornadiene)dirhodium(I)
- DI-M-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I)
- Chloronorbornadiene rhodium dimer
- 2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer
- Norbornadiene rhodium chloride dimer
- Di-μ-chlorobis(norbornadiene) dirhodiuM(I)
- Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 96%
- Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer
- 2,5-NORBORNADIENE-RHODIUM(I) CHLORIDE DIMER
- Di-^m-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
- BICYCLO[2.2.1]HEPTA-2,5-DIENE-RHODIUM(I) CHLORIDE DIMER
- BIS(NORBORNADIENE-MU-CHLORORHODIUM)
- CHLORO(2,5-NORBORNADIENE)RHODIUM(I) DIMER
- CHLORO(NORBORNADIENE)RHODATE (I) DIMER
- CHLORONORBORNADIENE RHODIUM(I) DIMER
- DI-MU-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I)
- Di-mu-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
- bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium
- Chloronorbornadiene rhodiuM(I) diMer, 99% 100MG
- Bis((mu-chloro)(norbornadiene)rhodium)
- Bis(chloro(eta4-norbornadiene)rhodium)
- Bis(mu-chloro)bis(norbornadiene)dirhodium
- Bis(mu-chloro)bis[(norbornadiene)rhodium]
- Bis[chloro(norbornadiene)rhodium]
- Dichloro(norbornadiene)dirhodium
- Dichlorobis(norbornadiene)dirhodium
- Di-mu-chlorobis(eta4-norbornadiene)dirhodium(I)
- Chloronorbornadiene rhodiuM(I) diMer,98% [Rh(NBD)Cl]2
- Bis(norbornadiene-mu-chlororhodium)
Chloronorbornadiene Rhodium(I) Dimer
- Di-Mu-chlorobis(norbornadiene)dirhodiuM
- Chloronorbornadiene rhodium(Ⅰ) dimer
- Chloronorbornadiene rhodium(I) dimer, [Rh(NBD)Cl]2
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER ISO 9001：2015 REACH
- Chloronorbornadienerhodium(I) Dimer, Rh 44.0%
- bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorod...
- )-bicyclo[2.2.1]hepta-2,5-diene]di-BC
- bis[(2,3,5,6-B7
- -chlorodirhodium
- Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 12257-42-0
- bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-;...
- Chiralyst P461
- Bis[(2,3,5,6-h)-bicyclo[2.2.1]hepta-2,5-diene]di-m-chlorodi-rhodium(I)
- Bis[(2,3,5,6-h)-bicyclo[2.2.1]hepta-2,5-dieneldi-n-chlorodi-rhodium(I)]
- [Rh(nbd)Cl]2
- Rhodium, bis[(2,3,5,6-h)-bicyclo[2.2.1]hepta-2,5-diene]di-m-chlorodi-
- 12257-42-0
- RhNBDCl2
- C14H16Cl2Rh2
