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BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)

BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Struktur
251567-28-9
CAS-Nr.
251567-28-9
Englisch Name:
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
Synonyma:
[Pd(NCOC2H4CO)(PPh3)2Br];BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II);bromo(n-succinimidyl)bis(triphenylphosphine)palladium(ii);trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II);bromopalladium, pyrrolidin-1-ide-2,5-dione, triphenylphospho...;bromopalladium(1+),pyrrolidin-1-ide-2,5-dione,triphenylphosphane;trans-BroMo(N-succiniMidyl)bis(triphenylphosphine)palladiuM(II),97%;BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II);trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
CBNumber:
CB5972889
Summenformel:
C40H37BrNO2P2Pd
Molgewicht:
812.01
MOL-Datei:
251567-28-9.mol

BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Eigenschaften

Schmelzpunkt:
223-228 °C (dec.) (lit.)
Aggregatzustand
solid
InChI
1S/2C18H15P.C4H5NO2.BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;6-3-1-2-4(7)5-3;;/h2*1-15H;1-2H2,(H,5,6,7);1H;/q;;;;+2/p-2
InChIKey
KYQYWUJRFOCJEW-UHFFFAOYSA-L
SMILES
Br[Pd]N1C(=O)CCC1=O.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

Sicherheit

WGK Germany  3
Speicherklasse 13 - Non Combustible Solids

BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II) may be used in the following processes:
  • As a catalyst for the preparation of 6-cyano-2-(3-fluoro-benzyl)-indole-1-carboxylic acid tert-butyl ester via Suzuki cross-coupling reaction between 1-boc-6-cyanoindole-2-boronic acid and 3-fluorobenzyl bromide. This method does not involve the use of strong bases or toxic reagents and also the use of this catalyst minimizes protodeboronation.
  • As a precatalyst for the Suzuki-Miyaura cross-coupling reaction between alkenyl tosylates and alkenyl MIDA boronates in the absence of phosphine ligands. For less activated alkenyl tosylate, the addition of tricyclohexylphosphine tetrafluoroborate improves the reactivity.

BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 30)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Alfa Chemistry
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Aladdin Scientific

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SHANGHAI KEAN TECHNOLOGY CO., LTD.
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Energy Chemical 021-021-58432009 400-005-6266
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Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696
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Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232
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Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091
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Sigma-Aldrich 021-61415566 800-8193336
orderCN@merckgroup.com China 51395 80

251567-28-9()Verwandte Suche:


  • [Pd(NCOC2H4CO)(PPh3)2Br]
  • BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
  • bromo(n-succinimidyl)bis(triphenylphosphine)palladium(ii)
  • trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
  • trans-BroMo(N-succiniMidyl)bis(triphenylphosphine)palladiuM(II),97%
  • bromopalladium, pyrrolidin-1-ide-2,5-dione, triphenylphospho...
  • BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
  • trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
  • bromopalladium(1+),pyrrolidin-1-ide-2,5-dione,triphenylphosphane
  • 251567-28-9
  • C40H34BrNO2P2Pd
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