BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) 物理性質(zhì)
- 融點 :
- 223-228 °C (dec.) (lit.)
- 外見 :
- solid
- InChI:
- 1S/2C18H15P.C4H5NO2.BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;6-3-1-2-4(7)5-3;;/h2*1-15H;1-2H2,(H,5,6,7);1H;/q;;;;+2/p-2
- InChIKey:
- KYQYWUJRFOCJEW-UHFFFAOYSA-L
- SMILES:
- Br[Pd]N1C(=O)CCC1=O.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
安全性情報
| WGK Germany |
3 |
|
|
| ストレージクラス |
13 - Non Combustible Solids |
|
|
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) 価格
もっと(1)
| メーカー |
製品番號 |
製品説明 |
CAS番號 |
包裝 |
価格 |
更新時間 |
購入 |
|
Sigma-Aldrich Japan
|
643742 |
97%
trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II) 97% |
251567-28-9 |
1g |
￥33000 |
2021-03-23 |
購入 |
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) 化學(xué)特性,用途語,生産方法
使用
trans-Bromo(
N-succinimidyl)bis(triphenylphosphine)palladium(II) may be used in the following processes:
- As a catalyst for the preparation of 6-cyano-2-(3-fluoro-benzyl)-indole-1-carboxylic acid tert-butyl ester via Suzuki cross-coupling reaction between 1-boc-6-cyanoindole-2-boronic acid and 3-fluorobenzyl bromide. This method does not involve the use of strong bases or toxic reagents and also the use of this catalyst minimizes protodeboronation.
- As a precatalyst for the Suzuki-Miyaura cross-coupling reaction between alkenyl tosylates and alkenyl MIDA boronates in the absence of phosphine ligands. For less activated alkenyl tosylate, the addition of tricyclohexylphosphine tetrafluoroborate improves the reactivity.
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) 上流と下流の製品情報
原材料
準備製品
BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) 生産企業(yè)
Global( 28)Suppliers
251567-28-9()キーワード:
- 251567-28-9
- [Pd(NCOC2H4CO)(PPh3)2Br]
- BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
- bromo(n-succinimidyl)bis(triphenylphosphine)palladium(ii)
- trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
- trans-BroMo(N-succiniMidyl)bis(triphenylphosphine)palladiuM(II),97%
- bromopalladium, pyrrolidin-1-ide-2,5-dione, triphenylphospho...
- BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II) BROMOBIS(PH3P)(N-SUCCINIMIDE)PD(II)
- trans-Bromo(N-succinimidyl)bis(triphenylphosphine)palladium(II)
- bromopalladium(1+),pyrrolidin-1-ide-2,5-dione,triphenylphosphane