Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat
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- CAS-Nr.
- 5522-66-7
- Bezeichnung:
- Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat
- Englisch Name:
- Protoporphyrin IX dimethyl ester
- Synonyma:
- Protoporphyrin dimethyl;dimethyl protoporphyrin IX;Protoporphyrin IX diMethyl es;Protoporphyrin IX dimethyl ester;Dimethylprotoporphyrin IX dimethyl ester;Protoporphyrin IX dimethyl ester, ≥95%(HPLC);Protoporphyrin IX dimethyl ester ~90% (HPLC);PROTOPORPHYRIN IX DIMETHYL ESTER FROM*OX HEMIN;dimethyl 8,13-divinyl-3,7,12,17-tetramethyl-21h,23h-porphine-2,18-dipropionate;dimethyl 3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphine-2,18-dipropionate
- CBNumber:
- CB9497515
- Summenformel:
- C36H38N4O4
- Molgewicht:
- 590.71
- MOL-Datei:
- 5522-66-7.mol
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Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat Eigenschaften
- Schmelzpunkt:
- 225-228 °C(lit.)
- Siedepunkt:
- 1017.0±65.0 °C(Predicted)
- Dichte
- 1.220±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- L?slichkeit
- DMSO: soluble
- Aggregatzustand
- crystal
- Farbe
- purple
- BRN
- 381574
- Stabilit?t:
- Light Sensitive
- InChIKey
- WASRLAPXOHTNAX-MFBGAUBSSA-N
- SMILES
- C(C1=C(C2=CC3=NC(=CC4=C(C=C)C(C)=C(N4)C=C4C(C)=C(CCC(=O)OC)C(=N4)C=C1N2)C(C)=C3C=C)C)CC(=O)OC |c:7,t:3,18,32|
- EPA chemische Informationen
- 21H,23H-Porphine-2,18-dipropanoic acid, 7,12-diethenyl-3,8,13,17-tetramethyl-, dimethyl ester (5522-66-7)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| WGK Germany |
3 |
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| F |
8-10-23 |
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| TSCA |
TSCA listed |
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| Speicherklasse |
11 - Combustible Solids |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H303 |
May be harmfulif swallowed |
Acute toxicity,oral |
Category 5 |
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P312 |
| H320 |
Causes eye irritation |
Serious eye damage/eye irritation |
Category 2B |
Warnung |
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P264, P305+P351+P338,P337+P313 |
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| Sicherheit |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
| P312 |
Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
| P337+P313 |
Bei anhaltender Augenreizung: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Protoporphyrin IX Dimethyl Ester is a derivative of Protoporphyrin IX (P839138), which is an important precursor to biologically essential prosthetic groups such as heme, cytochrome c, and chlorophylls.
l?uterung methode
The crude dimethyl ester (1g) in CHCl3 (200 mL) is mixed with pet ether (b 70-90o, 600mL), and any porphyrin (m > 260o) which is insoluble in this mixture is filtered off. The filtrate is passed through a column of CaCO3 [from CaCO3 (130g) which is kept overnight in a mixture of CHCl3/pet ether (b 70-90o, 1:3), and the slurry is poured into a glass tube (2.5 x 26cm) to form the column]. After all the filtrate is applied, the column is eluted with a solution of CHCl3/pet ether (b 70-90o, 1:3). All the coloured eluates are collected, evaporated at room temperature in a vacuum to give a residue (0.8g), m 208-211o. The residue (0.8g) in CHCl3 (66mL) is heated briefly to its boiling point, then boiling MeOH (198mL) is added immediately to it. The mixture is allowed to cool to room temperature, refrigerated for 2days and the solid is filtered off. The solid is washed on the filter funnel with CHCl3/MeOH (1:9, 50mL) and dried at 50o/vacuum (yield 0.62-0.66g). It can also be recrystallised by dissolving in as little hot dry *C6H6 as possible and left overnight at 20o, m 228-230o. It has also been purified by dissolving (0.4g) in CHCl3 (33mL) by boiling for a few minutes, then diluting with boiling MeOH (100mL) and refrigerating for 2days. The crystals are collected, washed with CHCl3/MeOH (1:9) and dried at 50o in a vacuum (yield 0.3g). The UV has max at 631, 576, 541, 506 and 407nm in CHCl3 and 601, 556 and 406nm in 25% HCl. [Ramsey Biochemical Preparations 3 39 1953, Beilstein 26 III/IV 3052.]
Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat Upstream-Materialien And Downstream Produkte
Upstream-Materialien
benzyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate
1H-Pyrrole-3-propanoic acid, 2,2'-methylenebis[4-methyl-5-[(phenylmethoxy)carbonyl]-, 3,3'-dimethyl ester
1H-Pyrrole-3-propanoic acid, 2,2'-methylenebis[5-carboxy-4-methyl-, α,α'-dimethyl ester
3,3'-(3,7,12,17-Tetramethyl-8,13-divinylporphin-2,18-diyl)di(propionsure)
3,3′-Dimethyl 2,2′-methylenebis[5-formyl-4-methyl-1H-pyrrole-3-propanoate]
Dinatrium-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat
Haematoporphyrin
Pinacol vinylboronate
Methanol
Downstream Produkte
Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 133)Lieferanten
5522-66-7(Dimethyl-3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionat)Verwandte Suche:
3,3'-(3,7,12,17-Tetramethyl-8,13-divinylporphin-2,18-diyl)di(propionsure)
Dimethyl ether
Dimethyl sebacate
Dimethylsulfat
Dimethylphthalat
Ethan
Dimethyladipat
4-(4-CHLORO-BENZYLOXY)-PHENYLAMINE
Dimethylcarbonat
Dimethylsulfid
Chlorthal-dimethyl
Dimethyloxalat
Dihydrogen-[3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphin-2,18-dipropionato(4-)-N21,N22,N23,N24]zincat(4-)
Vinylpropionat
Dimethylsulfoxid
N,N-Dimethylformamid
Dimethylfumarat
1,1,1-Trimethoxypentan
- methyl 3-[8,13-di(ethenyl)-18-(3-methoxy-3-oxo-propyl)-3,7,12,17-tetramethyl-22,23-dihydroporphyrin-2-yl]propanoate
- methyl 3-[8,13-di(ethenyl)-18-(3-methoxy-3-oxopropyl)-3,7,12,17-tetramethyl-22,23-dihydroporphyrin-2-yl]propanoate
- Protoporphyrin IX diMethyl es
- 21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethenyl-3,8,13,17-tetraMethyl-, 2,18-diMethyl ester
- ProtoporphyrinIX dimethyl ester,Dimethyl 8,13-divinyl-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate, Ooporpyhrin dimethyl ester
- dimethyl 8,13-divinyl-3,7,12,17-tetramethyl-21h,23h-porphine-2,18-dipropionate
- 7,12-diethenyl-3,8,13,17-tetramethyl-21H,23H-Porphine-2,18-dipropanoic acid- 2,18-dimethyl ester
- Dimethylprotoporphyrin IX dimethyl ester
- dimethyl protoporphyrin IX
- Ooporpyhrin dimethyl ester, Dimethyl 8,13-divinyl-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate
- 3,8,13,17-Tetramethyl-7,12-diethenyl-21H,23H-porphyrin-2,18-dipropionic acid dimethyl ester
- 7,12-Diethenyl-3,8,13,17-tetramethyl-21H,23H-porphyrin-2,18-bis(propionic acid methyl) ester
- Protoporphyrin dimethyl
- 3-[18-(3-keto-3-methoxy-propyl)-3,7,12,17-tetramethyl-8,13-divinyl-22,23-dihydroporphin-2-yl]propionic acid methyl ester
- dimethyl 3,8,13,17-tetramethyl-7,12-divinyl-21H,23H-porphine-2,18-dipropionate
- PROTOPORPHYRIN IX DIMETHYL ESTER FROM*OX HEMIN
- Protoporphyrin IX dimethyl ester
- Protoporphyrin IX dimethyl ester, ≥95%(HPLC)
- Protoporphyrin IX dimethyl ester ~90% (HPLC)
- Dimethyl 3,3'-(3,8,13,17-tetramethyl-7,12-divinylporphyrin-2,18-diyl)dipropionate
- 2,18-Dimethyl 7,12-diethenyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropanoate
- 5522-66-7
- porphine (porphyrin) ligand
