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ChemicalBook >> CAS DataBase List >>2-HYDROXYMETHYL-15-CROWN-5

2-HYDROXYMETHYL-15-CROWN-5

CAS No.
75507-25-4
Chemical Name:
2-HYDROXYMETHYL-15-CROWN-5
Synonyms
(1,4,7,10,13-Pentaoxacyclopentadecan-2-yl)methanol;Hydroxy-15-crown-5;2-HYDROXYMETHYL-15-CROWN-5;2-Hydroxymethyl-15-crown-5,96%;2-(HYDROXYMETHYL)-15-CROWN 5-ETHER;2-(Hydroxymethyl)-15-crown5-Ether>2-(Hydroxymethyl)-15-crown-5-ether 96%;1,4,7,10,13-Pentaoxacyclopentadec-2-ylmethanol;1,4,7,10,13-Pentaoxacyclopentadecane-3-methanol;1,4,7,10,13-PENTAOXACYCLOPENTADECANE-2-METHANOL
CBNumber:
CB0484891
Molecular Formula:
C11H22O6
Molecular Weight:
250.29
MDL Number:
MFCD00192215
MOL File:
75507-25-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 22:47:01
Product description Number Pack Size Price
2-Hydroxymethyl-15-crown-5 95% 388424 1g $107
2-(Hydroxymethyl)-15-crown 5-Ether >96.0%(GC) H0983 1g $103
2-(Hydroxymethyl)-15-crown 5-Ether >96.0%(GC) H0983 5g $302
2-(Hydroxymethyl)-15-crown-5-ether 96% OR10929 1g $66
2-(Hydroxymethyl)-15-crown-5-ether 96% OR10929 5g $258

2-HYDROXYMETHYL-15-CROWN-5 Properties

Boiling point 135 °C/1.5 mmHg (lit.)
Density 1.175 g/mL at 25 °C (lit.)
refractive index n20/D 1.479(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Liquid
Specific Gravity 1.17
color Colorless to Light yellow to Light orange
Water Solubility Soluble in water(58 g/L) (25°C).
BRN 3589706
InChI 1S/C11H22O6/c12-9-11-10-16-6-5-14-2-1-13-3-4-15-7-8-17-11/h11-12H,1-10H2
InChIKey YHIQMMGCRYKJLB-UHFFFAOYSA-N
SMILES OCC1COCCOCCOCCOCCO1
CAS DataBase Reference 75507-25-4(CAS DataBase Reference)
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
10
HS Code  29329990
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
2 1

2-HYDROXYMETHYL-15-CROWN-5 price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 388424 2-Hydroxymethyl-15-crown-5 95% 75507-25-4 1g $107 2026-04-30 Buy
TCI Chemical H0983 2-(Hydroxymethyl)-15-crown 5-Ether >96.0%(GC) 75507-25-4 1g $103 2026-04-30 Buy
TCI Chemical H0983 2-(Hydroxymethyl)-15-crown 5-Ether >96.0%(GC) 75507-25-4 5g $302 2026-04-30 Buy
Apolloscientific OR10929 2-(Hydroxymethyl)-15-crown-5-ether 96% 75507-25-4 1g $66 2026-06-04 Buy
Apolloscientific OR10929 2-(Hydroxymethyl)-15-crown-5-ether 96% 75507-25-4 5g $258 2026-06-04 Buy
Product number Packaging Price Buy
388424 1g $107 Buy
H0983 1g $103 Buy
H0983 5g $302 Buy
OR10929 1g $66 Buy
OR10929 5g $258 Buy

2-HYDROXYMETHYL-15-CROWN-5 Chemical Properties,Uses,Production

Chemical Properties

clear colorless to almost colorless liquid

Uses

2-Hydroxymethyl-15-crown-5 is used for chemical research.

Synthesis

In a four-necked flask equipped with a stirrer, reflux device, 200 mL of ethylene glycol dimethyl ether with 0.4 g of sodium hydroxide was added, stirred and heated to 75 C. Tetraethylene glycol--bromoalkyl ether 5 g was dissolved in 50 mL of ethylene glycol dimethyl ether and added dropwise to the reaction system. Then the reaction was stirred at 75-80C for 22 h. After the reaction, the sodium bromide was filtered out and the solvent was evaporated to obtain a yellow viscous oily substance of 4.5 g. The bromine mass fraction was measured to be 0.71%. 80mL of oily material without separation directly added to 1 mol / L hydrochloric acid solution, reflux 4h, precipitated white solid. After cooling, the solid (triphenylmethanol) was filtered out and extracted with chloroform for 3-5 times, the extracts were combined, dried with anhydrous magnesium sulfate and evaporated with chloroform under reduced pressure. The residue was purified by chromatography with aluminum chloride (neutral), and the eluent was acetone-hexane (7:3, v/v). The solvent was removed by decompression evaporation to give 2-hydroxymethyl-15-crown-5 as a yellow oil, 2.03 g, in 87% yield.

2-HYDROXYMETHYL-15-CROWN-5 Preparation Products And Raw materials

Raw materials

Preparation Products

2-HYDROXYMETHYL-15-CROWN-5 Suppliers

Global( 89)Suppliers
Supplier Tel Email Country ProdList Advantage
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 9599 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30224 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739 info@dycnchem.com China 52704 58
GIHI CHEMICALS CO.,LIMITED
+86-571-86217390; +8618058761490 info@gihichemicals.com China 49892 58
HANGZHOU LEAP CHEM CO., LTD.
+86-571-87711850 market18@leapchem.com China 43333 58
Aladdin Scientific
tp@aladdinsci.com United States 57505 58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
+8618950047208 ellena@amitychem.com China 43414 58
Chongqing jooe co., ltd
+undefined86-15223382610 info@jooe.com China 15971 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131956 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32343 55

View Lastest Price from 2-HYDROXYMETHYL-15-CROWN-5 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-HYDROXYMETHYL-15-CROWN-5 pictures 2021-08-12 2-HYDROXYMETHYL-15-CROWN-5
75507-25-4
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
1,4,7,10,13-Pentaoxacyclopentadecane-3-methanol Hydroxy-15-crown-5 2-Hydroxymethyl-15-crown-5,96% 2-HYDROXYMETHYL-15-CROWN-5 2-(HYDROXYMETHYL)-15-CROWN 5-ETHER 2-(HYDROXYMETHYL)-1,4,7,10,13-PENTAOXACYCLOPENTADECAN 2-(HYDROXYMETHYL)-1,4,7,10,13-PENTAOXACYCLOPENTADECANE 1,4,7,10,13-PENTAOXACYCLOPENTADECANE-2-METHANOL 2-(Hydroxymethyl)-15-crown-5-ether 96% 2-(Hydroxymethyl)-15-crown5-Ether> 1,4,7,10,13-Pentaoxacyclopentadec-2-ylmethanol (1,4,7,10,13-Pentaoxacyclopentadecan-2-yl)methanol 75507-25-4 77507-25-4 45507-25-4 C11H22O6 Chelation/Complexation Compounds Synthetic Reagents Crown Ethers Macrocycles for Host-Guest Chemistry Crown Ethers Functional Materials Macrocycles for Host-Guest Chemistry
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