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ChemicalBook >> CAS DataBase List >>4-Chlorobenzyl alcohol

4-Chlorobenzyl alcohol

CAS No.
873-76-7
Chemical Name:
4-Chlorobenzyl alcohol
Synonyms
(4-CHLOROPHENYL)METHANOL;4-chlorobenzyl;ai3-20628;p-Chlorotoluol;RARECHEM AL BD 0077;4-Chlorobenzyl alcoh;p-chloro-benzylalcoho;Chlorophenyl Methanol;P-CHLOROBENZYL ALCOHOL;LABOTEST-BB LT02085068
CBNumber:
CB2714497
Molecular Formula:
C7H7ClO
Molecular Weight:
142.58
MDL Number:
MFCD00004652
MOL File:
873-76-7.mol
MSDS File:
SDS
Last updated:2026-05-28 00:44:21
Product description Number Pack Size Price
4-Chlorobenzyl alcohol 99% C27115 25g $132
4-Chlorobenzyl Alcohol >99.0%(GC) C0565 25g $85
4-Chlorobenzyl alcohol Asreported 269374 50g $373
4-Chlorobenzyl alcohol Asreported 269374 100g $519
4-Chlorobenzyl alcohol Asreported 269374 250g $711
More product size

4-Chlorobenzyl alcohol Properties

Melting point 68-71 °C(lit.)
Boiling point 234 °C(lit.)
Density 1.1104 (rough estimate)
refractive index 1.5390 (estimate)
Flash point 70 °C
storage temp. Sealed in dry,Room Temperature
solubility 2.5g/l
pka 14.16±0.10(Predicted)
form Crystalline Needles or Powder
color Almost white to beige
Water Solubility Soluble in water (2.5 mg/ml at 20°C), and methanol.
BRN 636502
Stability Stable. Incompatible with acid chlorides, acid anhydrides, acids, oxidizing agents. Combustible.
Major Application pharmaceutical
InChI 1S/C7H7ClO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
InChIKey PTHGDVCPCZKZKR-UHFFFAOYSA-N
SMILES OCc1ccc(Cl)cc1
CAS DataBase Reference 873-76-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII GF8BS53B6V
NIST Chemistry Reference 4-Chlorobenzyl alcohol(873-76-7)
EPA Substance Registry System 4-Chlorobenzenemethanol (873-76-7)
UNSPSC Code 77101502
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
RTECS  DN9242000
HS Code  29062900
Storage Class 11 - Combustible Solids
NFPA 704
1
0 0

4-Chlorobenzyl alcohol price More Price(75)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich C27115 4-Chlorobenzyl alcohol 99% 873-76-7 25g $132 2026-04-30 Buy
TCI Chemical C0565 4-Chlorobenzyl Alcohol >99.0%(GC) 873-76-7 25g $85 2026-04-30 Buy
Usbiological 269374 4-Chlorobenzyl alcohol Asreported 873-76-7 50g $373 2026-06-03 Buy
Usbiological 269374 4-Chlorobenzyl alcohol Asreported 873-76-7 100g $519 2026-06-03 Buy
Usbiological 269374 4-Chlorobenzyl alcohol Asreported 873-76-7 250g $711 2026-06-03 Buy
Product number Packaging Price Buy
C27115 25g $132 Buy
C0565 25g $85 Buy
269374 50g $373 Buy
269374 100g $519 Buy
269374 250g $711 Buy

4-Chlorobenzyl alcohol Chemical Properties,Uses,Production

Description

It is usually used as the intermediate in organic synthesis and pharmaceutical industry. Specifically, this chemical can react with o-xylene in the presence of HAuCl4 or AuCl3 at 80 ℃ to generate the corresponding benzylated product.1 Moreover, the acetylation of 4-chlorobenzyl alcohol in presence of catalytic amounts of Ce(OTf)4 has been performed in acetic acid to produce the desired esters in the excellent yields.2 In addition, this chemical may function as the raw material to produce its corresponding carboxylic acids and ketones in good yields through the oxidation reaction by using hydrogen peroxide and cobalt(Ⅱ) complex.3 Besides, the formylation and acetylation of 4-chlorobenzyl alcohol may be carried out in the presence of Silphos [PCl3?n(SiO2)n] in ethyl formate and ethyl acetate.4

Referrence

  1. Mertins, K.; Lovel, I.; Kischel, J.; Zapf, A.; Beller, M., Gold-catallyzed benzylation of arenes and heteroarenes. Adv. Synth. Catal. 2006, 348, 691-695.
  2. Iranpoor, N.; Shekarriz, M., Catalytic Esterification of Alcohols, Carboxylic Acids and Transesterification Reactions with Cerium(IV) Triflate. Bull. Chem. Soc. Jpn. 1999, 72, 455-458.
  3. Das, S.; Punniyamurthy, T., Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide. Tetrahedron Lett. 2003, 44, 6033-6035.
  4. Iranpoor, N.; Firouzabadi, H.; Jamalian, A., Silphos PCl3-n(SiO2)(n) : a heterogeneous phosphine reagent for formylation and acetylation of alcohols and amines with ethyl formate and acetate. Tetrahedron Lett. 2005, 46, 7963-7966.

Chemical Properties

white crystalline powder

Uses

Reagent for carboxyl group protection.

Uses

4-Chlorobenzyl alcohol acts as a reagent for the protection of carboxyl groups as their 4-chlorobenzyl esters, more stable to acid than the corresponding benzyl esters. It is used as solvent in paint stripper and waterborne coatings. It acts as curing agent. It is also used in pharmaceuticals, cosmetics, preservatives, and flavoring & fragrance agents.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 681, 1960 DOI: 10.1021/ja01488a045

Global( 439)Suppliers
Supplier Tel Email Country ProdList Advantage
Shandong Vital Biotechnology Co., Ltd.
+86-17860230571 biotechcaroline@gmail.com China 87 58
Speranza Chemical Co., Ltd.
+86-86-075521030354 +86-18688942810 sophieliu@speranzachem.com China 923 55
Hebei Chuanghai Biotechnology Co., Ltd
+86-15350571055 Sibel@chuanghaibio.com China 8738 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-86-13131129325 sales1@chuanghaibio.com China 5220 58
Frapp's ChemicalNFTZ Co., Ltd.
+86 (576) 8169-6106 sales@frappschem.com China 880 50
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29640 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 14026 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2988 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29812 58
Xiamen AmoyChem Co., Ltd
+86-86-5926051114 sales@amoychem.com China 6366 58

Related Qustion

Ask a question
Q:What is 4-Chlorobenzyl alcohol used for?wipes - Dec 4,2025
A:4-Chlorobenzyl alcohol is primarily used as a chemical intermediate in the production of various fine chemicals. Its main function is as a structural unit in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds. In the laboratory, it is used as a reagent, particularly for protecting carboxyl groups in multi-step organic synthesis processes. Industrially, it is used as a solvent, for example, in the formulation of paint removers and water-based coatings, and also as a curing agent. Furthermore, it is added to products such as cosmetics and preservatives.

View Lastest Price from 4-Chlorobenzyl alcohol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Chlorobenzyl alcohol pictures 2026-07-30 4-Chlorobenzyl alcohol
873-76-7
$100.00 25kg 98% 300 tons Speranza Chemical Co., Ltd.
4-Chlorobenzyl alcohol pictures 2026-05-28 4-Chlorobenzyl alcohol
873-76-7
$10.00-30.00 10kg 99% 100000kg Hebei Chuanghai Biotechnology Co,.LTD
4-Chlorobenzyl alcohol pictures 2026-04-27 4-Chlorobenzyl alcohol
873-76-7
1kg 98% 100tons Shandong Vital Biotechnology Co., Ltd.
4-CHLOROBENZYL ALCOHOL 4-chlorobenzylic alcohol 4-Chlorobenzylalcohol,99% LABOTEST-BB LT02085068 P-CHLOROBENZYL ALCOHOL RARECHEM AL BD 0077 4-chloro-benzenemethano 4-chlorobenzenemethanol ai3-20628 Benzenemethanol, 4-chloro- Benzyl alcohol, p-chloro- p-chloro-benzylalcoho 4-Chlorobenzyl alcohol 98% 4- CHLOROMETHYL ALCOHOL PARA-CHLOROBENZYLALCOHOL p-Chlorotoluol 1-Hydroxymethyl-4-chlorobenzene 4-Chlorobenzyl alcoh Chlorophenyl Methanol 4-CHLOROBENZYL ALCOHOL FOR SYNTHESIS 4-Chlorobenzyl Alcohol > 4-Chloro benzyl alcohol, 98%+ 4-Chlorobenzyl Alcohol/Para Chlorobenzyl Alcohol 13C6]-4-Chlorobenzyl alcohol Oxiconazole Impurity 12 Chlorpheniramine Impurity 43 (4-CHLOROPHENYL)METHANOL 4-chlorobenzyl 873-76-7 837-76-7 8763-76-7 C7H7ClO Oxygen Compounds Organic Building Blocks C7 to C8 Alcohols Building Blocks Building Blocks C7 to C8 Chemical Synthesis Organic Building Blocks Oxygen Compounds Benzhydrols, Benzyl & Special Alcohols Alcohol Alcohols Chlorine Compounds C7 to C8 Oxygen Compounds Alcohols and Derivatives
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