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ChemicalBook >> CAS DataBase List >>(+/-)1-(1-Naphthyl)ethylamine

(+/-)1-(1-Naphthyl)ethylamine

CAS No.
42882-31-5
Chemical Name:
(+/-)1-(1-Naphthyl)ethylamine
Synonyms
1-(1-NAPHTHYL)ETHYLAMINE;1-NAPHTHYLETHYLAMINE;1-(1-Napthyl)ethylamine;Naphthylethylamine;5,6-Dihydro-α7,8-Dihydro-α(+/-)1-(1-Naphthyl)e;Cinacalcet Impurity 48;1-(1-Naphtyl)ethanamine;1-Naphthaleneethylamine
CBNumber:
CB4700526
Molecular Formula:
C12H13N
Molecular Weight:
171.24
MDL Number:
MFCD00004014
MOL File:
42882-31-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 01:27:02
Product description Number Pack Size Price
1-(1-Naphthyl)ethylamine 98% 294926 5g $56.4
DL-1-(1-Naphthyl)ethylamine >98.0%(GC)(T) N0523 25mL $125
DL-1-(1-Naphthyl)ethylamine >98.0%(GC)(T) N0523 500mL $1229
1-(1-Naphthyl)ethylamine TRC-N372510-500MG 500mg $65
1-(1-Naphthyl)ethylamine TRC-N372510-2.5G 2.5g $91
More product size

(+/-)1-(1-Naphthyl)ethylamine Properties

Boiling point 156 °C15 mm Hg(lit.)
Density 1.063 g/mL at 25 °C(lit.)
refractive index n20/D 1.621(lit.)
Flash point >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in alcohol, ether; insoluble in H2O
form clear liquid
pka 9.26±0.40(Predicted)
color Colorless to Yellow to Green
optical activity Consistent with structure
Sensitive Air Sensitive
BRN 3197375
InChI InChI=1S/C12H13N/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-9H,13H2,1H3
InChIKey RTCUCQWIICFPOD-UHFFFAOYSA-N
SMILES C12C=CC=CC1=CC=CC=2C(N)C
CAS DataBase Reference 42882-31-5(CAS DataBase Reference)
EWG's Food Scores 1
EPA Substance Registry System 1-Naphthalenemethanamine, .alpha.-methyl- (42882-31-5)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38-34-25
Safety Statements  26-36-45-36/37/39
RIDADR  2735
WGK Germany  3
10-34
TSCA  TSCA listed
HazardClass  8
PackingGroup  III
HS Code  29214990
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
REACH Registrations Active
NFPA 704
1
2 0

(+/-)1-(1-Naphthyl)ethylamine price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 294926 1-(1-Naphthyl)ethylamine 98% 42882-31-5 5g $56.4 2023-06-20 Buy
TCI Chemical N0523 DL-1-(1-Naphthyl)ethylamine >98.0%(GC)(T) 42882-31-5 25mL $125 2026-04-30 Buy
TCI Chemical N0523 DL-1-(1-Naphthyl)ethylamine >98.0%(GC)(T) 42882-31-5 500mL $1229 2026-04-30 Buy
TRC TRC-N372510-500MG 1-(1-Naphthyl)ethylamine 42882-31-5 500mg $65 2026-06-03 Buy
TRC TRC-N372510-2.5G 1-(1-Naphthyl)ethylamine 42882-31-5 2.5g $91 2026-06-03 Buy
Product number Packaging Price Buy
294926 5g $56.4 Buy
N0523 25mL $125 Buy
N0523 500mL $1229 Buy
TRC-N372510-500MG 500mg $65 Buy
TRC-N372510-2.5G 2.5g $91 Buy

(+/-)1-(1-Naphthyl)ethylamine Chemical Properties,Uses,Production

Chemical Properties

Colorless or yellow liquidcrystalline

Uses

1-(1-Naphthyl)ethylamine is used in the enzymic resolution of amines. A chirality modifier.

General Description

The adsorption of 1-(1-naphthyl)ethylamine on platinum surfaces has been characterized by reflection-absorption infrared spectroscopy and temperature-programmed desorption both under ultrahigh vacuum and in situ from liquid solutions.

Synthesis

1'-Acetonaphthone

941-98-0

(+/-)1-(1-Naphthyl)ethylamine

42882-31-5

General procedure for the synthesis of 1-naphthylethylamine from 1-naphthylethanone: The corresponding ketone (10 mmol, specifically 1.14 g of 1a, 0.98 g of 1b, 1.48 g of 1c, 1.46 g of 1d, 1.46 g of 1e, 1.32 g of 1f, 1.20 g of 1g, 1.70 g of 1h, 1.70 g of 1i) was mixed with hydroxylamine hydrochloride ( 15 mmol, 1.04 g), ammonium formate (60 mmol, 3.78 g) and zinc powder (30 mmol, 1.96 g) in methanol (30 mL) and the reaction was stirred under reflux conditions. After completion of the reaction, the reaction mixture was filtered through Celite. The filtrate was subjected to vacuum rotary evaporation to remove the solvent. The residue was treated with concentrated hydrochloric acid followed by the addition of 4 mL of HCl solution and 30 mL of water and extracted with ether (2 x 20 mL) to remove organic impurities. The aqueous phase was adjusted to pH=10 with ammonia and extracted with dichloromethane (4 x 25 mL). The organic phases were combined, washed with saturated saline, dried over anhydrous sodium sulfate, and finally the solvent was removed in vacuum to obtain the target product 1-naphthylethylamine.

References

[1] Tetrahedron Letters, 2011, vol. 52, # 12, p. 1310 - 1312
[2] Journal of Medicinal Chemistry, 2006, vol. 49, # 21, p. 6197 - 6208
[3] Patent: WO2008/58235, 2008, A2. Location in patent: Page/Page column 23-24
[4] Synthetic Communications, 2011, vol. 41, # 3, p. 341 - 346
[5] Molecules, 2014, vol. 19, # 12, p. 21386 - 21397

344248-49-3
42882-31-5
Synthesis of (+/-)1-(1-Naphthyl)ethylamine from Phosphinic amide, N-[1-(1-naphthalenyl)ethyl]-P,P-diphenyl-
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View Lastest Price from (+/-)1-(1-Naphthyl)ethylamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
 1- (1-naphthyl) Ethylamine  pictures 2026-05-28 1- (1-naphthyl) Ethylamine
42882-31-5
$2.00-5.00 1kg 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
(+/-)1-(1-Naphthyl)ethylamine  pictures 2025-11-18 (+/-)1-(1-Naphthyl)ethylamine
42882-31-5
$1.10 1g 99.00% 100 Tons Min Dideu Industries Group Limited
Dl-1-(1-Naphthyl)Ethylamine pictures 2025-04-04 Dl-1-(1-Naphthyl)Ethylamine
42882-31-5
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
(±)-1-(1-Naphthyl)ethylamine,98% (±)-α-Methyl-1-naphthalenemethylamine, (±)-1-(1-Naphthyl)ethylamine 1-Naphthalen-1-ylethanamine (±)-1-(1-Aminoethyl)naphthalene rac-(1R*)-1-(1-Naphtyl)ethanamine rac-[(R*)-1-(1-Naphtyl)ethyl]amine 1-(1-Naphtyl)ethanamine α-Methyl-1-naphthalenemethanamine α-Methylnaphthalene-1-methanamine 1-(Naphth-1-yl)ethylamine 1-(1-Naphthyl)ethylaMine 98% 1-Naphthaleneethylamine 1-Naphthalenemethanamine, .alpha.-methyl- (n)-1-(1-naphthyl)ethylamine (+/-)1-(1-Naphthyl)ethylamine (+/-)1-(1-Naphthyl)e 1-(1-naphthyl)ethanamine(SALTDATA: FREE) Cinacalcet Intermediate 2 (R)-.alpha.-Methyl-1-naphthalenemethanamine (+/-)-1-(1-NPHTHYL)ETHYLAMNE (R)-alpha-Methyl-1-naphthalenemethanamine (+)-1-(1-Naphtyl)ethylamine (+/-)-1-naphthalenemethanamin (R)-(+)-1-(1-Nphthyl)ethylamne Naphthylethylamine DL-1-(1-Naphthyl)ethylamine (+/-)1-(1-phthyl)ethylamine DL-ALPHA-(1-AMINOETHYL)NAPHTHALENE DL-ALPHA-(1-NAPHTHYL)ETHYLAMINE DL-1-(1-NAPHTHYL)ETHYLAMINE (+/-)-alpha-Methyl-1-naphthalenemethylamine 1-NAPHTHALEN-1-YL-ETHYLAMINE 5,6-Dihydro-&alpha -methyl-N-[3-[3-(trifluoromethyl)phenyl]propyl]-1-naphthalenemethanamine Hydrochloride Cinacalcet Impurity 48 7,8-Dihydro-&alpha DL-1-(1-Naphthyl)ethylamine> 1-(1-Naphthyl)ethylamine, 95%, for synthesis 1-Naphthalenemethanamine, α-methyl- (+/-)1-(1-Naphthyl)ethylamine ISO 9001:2015 REACH 1-(Naphthalene-1-yl)ethaneamine TIANFU CHEM (+/-)1-(1-Naphthyl)ethylamine (+/-)-1-(1-naphthyl)ethylamine DL-1-(Naphthalen-1-yl)ethanamine 1-(1-Naphthyl)ethylamine HCl alpha-Methyl-1-naphthalenemethanamine 1-Naphthalenemethanamine, a-methyl- DL-1-(1-Napthyl )ethylamine (±)-1-(1-Naphthyl)ethylamine 1-(1-Napthyl)ethylamine 1-(1-NAPHTHYL)ETHYLAMINE 1-NAPHTHYLETHYLAMINE 42882-31-5 C12H13N1 C10H7CHCH3NH2 AMINE Nitrogen Compounds Organic Building Blocks
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