4-Bromo-1-methoxy-2-methylbenzene
- CAS No.
- 14804-31-0
- Chemical Name:
- 4-Bromo-1-methoxy-2-methylbenzene
- Synonyms
- 4-BROMO-2-METHYLANISOLE;Bromomethoxytoluene;Methyl-4-bromoanisole;2-METHYL-4-BROMOANISOLE;4-Allyloxy BroMo Benzene;2-Methoxy-5-bromotoluene;5-BROMO-2-METHOXYTOLUENE;4-BROMO-2-METHYLANISOLE 98%;5-Bromo-2-methoxytoluene >5-BROMO-2-METHOXYTOLUENE 98+%
- CBNumber:
- CB5672408
- Molecular Formula:
- C8H9BrO
- Molecular Weight:
- 201.06
- MDL Number:
- MFCD01321139
- MOL File:
- 14804-31-0.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-Bromo-2-methylanisole 98% | 523054 | 25g | $116 |
| 5-Bromo-2-methoxytoluene >98.0%(GC) | B1910 | 5g | $54 |
| 5-Bromo-2-methoxytoluene >98.0%(GC) | B1910 | 25g | $210 |
| 5-Bromo-2-methoxytoluene, min. 98% min.98% | 06-0079 | 25g | $73 |
| 5-Bromo-2-methoxytoluene, min. 98% min.98% | 06-0079 | 100g | $185 |
| More product size | |||
| Melting point | 66-69 °C(lit.) |
|---|---|
| Boiling point | 124-125°C 25mm |
| Density | 1.378±0.06 g/cm3 (20 ºC 760 Torr) |
| Flash point | 124-125°C/25mm |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | White to Light yellow |
| BRN | 208224 |
| InChI | 1S/C8H9BrO/c1-6-5-7(9)3-4-8(6)10-2/h3-5H,1-2H3 |
| InChIKey | UDLRGQOHGYWLCS-UHFFFAOYSA-N |
| SMILES | COc1ccc(Br)cc1C |
| CAS DataBase Reference | 14804-31-0(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xi | |||||||||
| Safety Statements | 24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 29093090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
4-Bromo-1-methoxy-2-methylbenzene price More Price(67)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 523054 | 4-Bromo-2-methylanisole 98% | 14804-31-0 | 25g | $116 | 2026-04-30 | Buy |
| TCI Chemical | B1910 | 5-Bromo-2-methoxytoluene >98.0%(GC) | 14804-31-0 | 5g | $54 | 2026-04-30 | Buy |
| TCI Chemical | B1910 | 5-Bromo-2-methoxytoluene >98.0%(GC) | 14804-31-0 | 25g | $210 | 2026-04-30 | Buy |
| Strem Chemicals | 06-0079 | 5-Bromo-2-methoxytoluene, min. 98% min.98% | 14804-31-0 | 25g | $73 | 2026-04-30 | Buy |
| Strem Chemicals | 06-0079 | 5-Bromo-2-methoxytoluene, min. 98% min.98% | 14804-31-0 | 100g | $185 | 2026-04-30 | Buy |
4-Bromo-1-methoxy-2-methylbenzene Chemical Properties,Uses,Production
Chemical Properties
colorless to light yellow liquid
Uses
4-Bromo-2-methylanisole may be used in the synthesis of 4-isopropyl-2-methylphenol and 4-methoxy-3-methylphenol.
General Description
4-Bromo-2-methylanisole can be prepared by the bromination of o-methylanisole (2-methylanisole). It can also be prepared via reaction between 1-butyl-3-methylimidazolium tribromide [(Bmim)Br3] and an activated aromatic compound. It participates as a substrate for the a-arylation of sulphonamide in a study.
Synthesis
578-58-5
14804-31-0
General procedure for the synthesis of 2-methyl-4-bromoanisole from 2-methylanisole: In a dry 45 mL reaction tube equipped with a magnetic stirrer (note: air was not removed from the reaction tube), 1 mL of [Bmim]NO3, 0.5 mmol of 2-methylanisole and 0.25 mmol of Br2 were added. The reaction tube was then sealed and the reaction was carried out at 80 °C for 24 hours. Upon completion of the reaction, the mixture was cooled to room temperature and the reaction was terminated by the addition of 3 mL of water. The target product 2-methyl-4-bromoanisole was extracted with dichloromethane (3 x 10 mL). The reaction mixture was analyzed by gas chromatography (GC) to determine the GC yield of the product. In another parallel experiment, the product was purified by column chromatography and structurally characterized using 1H NMR and 13C NMR.
References
[1] Helvetica Chimica Acta, 1983, vol. 66, # 4, p. 1068 - 1077
[2] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[3] Chemistry - A European Journal, 2015, vol. 21, # 34, p. 11976 - 11979
[4] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999, vol. 38, # 5, p. 603 - 604
4-Bromo-1-methoxy-2-methylbenzene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | 52513593@qq.com | CHINA | 2972 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569266 +86-17392581500 | 1015@dideu.com | China | 3861 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
View Lastest Price from 4-Bromo-1-methoxy-2-methylbenzene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-24 | 4-BROMO-2-METHYLANISOLE
14804-31-0
|
$1.00 | 1g | 98%min | Career Henan Chemical Co |
-
- 4-BROMO-2-METHYLANISOLE
14804-31-0
- $1.00
- 98%min
- Career Henan Chemical Co
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