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ChemicalBook >> CAS DataBase List >>4-BENZYLOXY-2-HYDROXYBENZALDEHYDE

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE

CAS No.
52085-14-0
Chemical Name:
4-BENZYLOXY-2-HYDROXYBENZALDEHYDE
Synonyms
4-Benzyloxysalicylaldehyde;4-BENZYLOXY-2-HYDROXYBENZALDEHYDE;2-hydroxy-4-phenylmethoxybenzaldehyde;Benzaldehyde, 2-hydroxy-4-(phenylmethoxy)-;4-benzenemethoxy-2-hydroxybenzenemethylaldehyde
CBNumber:
CB6170446
Molecular Formula:
C14H12O3
Molecular Weight:
228.24
MDL Number:
MFCD01075698
MOL File:
52085-14-0.mol
MSDS File:
SDS
Last updated:2026-05-28 01:21:33
Product description Number Pack Size Price
4-(Benzyloxy)-2-hydroxybenzaldehyde AldrichCPR CDS001087 250MG $77.9
4-(Benzyloxy)-2-hydroxybenzaldehyde min. 98.0 % H1904 1G $45
4-(Benzyloxy)-2-hydroxybenzaldehyde min. 98.0 % H1904 5G $135
4-(Benzyloxy)-2-hydroxybenzaldehyde CCA08514 25g $295
4-(Benzyloxy)-2-hydroxybenzaldehyde >98% OR315520 5g $25

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Properties

Melting point 78-80°C
Boiling point 165-175 °C(Press: 1 Torr)
Density 1.238±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka 7.80±0.10(Predicted)
form solid
Appearance Light brown to brown Solid
Sensitive Air Sensitive
BRN 982995
InChI 1S/C14H12O3/c15-9-12-6-7-13(8-14(12)16)17-10-11-4-2-1-3-5-11/h1-9,16H,10H2
InChIKey AMLKEDBYDOCGEG-UHFFFAOYSA-N
SMILES Oc1cc(OCc2ccccc2)ccc1C=O
UNSPSC Code 12352200

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi,N
Risk Statements  36/37/38-50-43
Safety Statements  26-36-61-36/37
WGK Germany  WGK 3
HS Code  2912210000
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1
NFPA 704
0
2 0

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE price More Price(56)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich CDS001087 4-(Benzyloxy)-2-hydroxybenzaldehyde AldrichCPR 52085-14-0 250MG $77.9 2026-04-30 Buy
TCI Chemical H1904 4-(Benzyloxy)-2-hydroxybenzaldehyde min. 98.0 % 52085-14-0 1G $45 2026-04-30 Buy
TCI Chemical H1904 4-(Benzyloxy)-2-hydroxybenzaldehyde min. 98.0 % 52085-14-0 5G $135 2026-04-30 Buy
Biosynth CCA08514 4-(Benzyloxy)-2-hydroxybenzaldehyde 52085-14-0 25g $295 2026-06-04 Buy
Apolloscientific OR315520 4-(Benzyloxy)-2-hydroxybenzaldehyde >98% 52085-14-0 5g $25 2026-06-04 Buy
Product number Packaging Price Buy
CDS001087 250MG $77.9 Buy
H1904 1G $45 Buy
H1904 5G $135 Buy
CCA08514 25g $295 Buy
OR315520 5g $25 Buy

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Chemical Properties,Uses,Production

Synthesis

Benzyl bromide

100-39-0

2,4-Dihydroxybenzaldehyde

95-01-2

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE

52085-14-0

2,4-Dihydroxybenzaldehyde (3.0 g, 1.0 eq.) was dissolved in acetonitrile (220 mL), sodium bicarbonate (2.2 eq.) was added at room temperature and stirred for 45 minutes. Subsequently, benzyl bromide (1.1 eq.) was slowly added to the reaction system. The reaction mixture was heated to reflux and stirred continuously. Upon completion of the reaction, the reaction was quenched with deionized water (100 mL) and subsequently extracted with ethyl acetate (3 x 25 mL). The organic phases were combined, washed with saturated saline (2 × 15 mL), dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to remove the solvent, to afford the crude product 4-phenylmethoxy-2-hydroxybenzaldehyde 12 as a white solid, which could be used in subsequent reactions without further purification.

References

[1] Bioorganic and Medicinal Chemistry, 2013, vol. 21, # 15, p. 4502 - 4510
[2] Synlett, 2011, # 11, p. 1605 - 1607
[3] Organic Process Research and Development, 2011, vol. 15, # 5, p. 1149 - 1162
[4] Tetrahedron Letters, 2013, vol. 54, # 31, p. 4121 - 4124
[5] Organic Letters, 2008, vol. 10, # 21, p. 5007 - 5010

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Preparation Products And Raw materials

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Suppliers

Global( 97)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29792 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 9542 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739 info@dycnchem.com China 52705 58
Changzhou Anxuan Chemical Co., Ltd
+86-0519-89882563 +86-18961279162 andy@anxuanchem.com China 4327 58
Nextpeptide Inc
+86-0571-81612335 +8613336028439 sales@nextpeptide.com China 19908 58
Hangzhou MolCore BioPharmatech Co.,Ltd.
+86-057181025280; +8617767106207 sales@molcore.com China 49734 58
PT CHEM GROUP LIMITED
+86-85511178; peter68@ptchemgroup.com China 35425 58
GIHI CHEMICALS CO.,LIMITED
+86-571-86217390; +8618058761490 info@gihichemicals.com China 49969 58
Protheragen-ING
+16313385890 info@protheragen-ing.com United States 3868 58

View Lastest Price from 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-BENZYLOXY-2-HYDROXYBENZALDEHYDE pictures 2020-01-08 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE
52085-14-0
$1.00 1KG 98%-99.9% 200KG Career Henan Chemical Co

4-BENZYLOXY-2-HYDROXYBENZALDEHYDE Spectrum

Benzaldehyde, 2-hydroxy-4-(phenylmethoxy)- 2-hydroxy-4-phenylmethoxybenzaldehyde 4-BENZYLOXY-2-HYDROXYBENZALDEHYDE 4-Benzyloxysalicylaldehyde 4-benzenemethoxy-2-hydroxybenzenemethylaldehyde 52085-14-0 ALDEHYDE
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