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ChemicalBook >> CAS DataBase List >>Ethyl 5-broMo-2-furoate, 97+%

Ethyl 5-broMo-2-furoate, 97+%

CAS No.
6132-37-2
Chemical Name:
Ethyl 5-broMo-2-furoate, 97+%
Synonyms
Ethyl 5-bromofuran-2-carboxylate;Ethyl 5-broMo-2-furoate;Ethyl 5-broMo-2-furoate, 97+%;ethyl 5-broMo-2-furancarboxylate;5-Bromo-2-furancarboxylic Acid Ethyl Ester;2-Furancarboxylic acid, 5-broMo-, ethyl ester
CBNumber:
CB62549097
Molecular Formula:
C7H7BrO3
Molecular Weight:
219.03
MDL Number:
MFCD00092362
MOL File:
6132-37-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:28:18
Product description Number Pack Size Price
Ethyl 5-Bromo-2-furancarboxylate >97.0%(GC) E1285 1g $95
Ethyl 5-Bromo-2-furancarboxylate >97.0%(GC) E1285 5g $378
Ethyl 5-bromo-2-furancarboxylate ≥97%(GC) 44457 1G $71.41
Ethyl 5-bromo-2-furancarboxylate ≥97%(GC) 44457 5G $217.83
Ethyl 5-bromofuran-2-carboxylate 97% E45937 250mg $19

Ethyl 5-broMo-2-furoate, 97+% Properties

Melting point 17 °C
Boiling point 234 °C
Density 1.533±0.06 g/cm3(Predicted)
refractive index 1.52
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
InChI InChI=1S/C7H7BrO3/c1-2-10-7(9)5-3-4-6(8)11-5/h3-4H,2H2,1H3
InChIKey GVAPLPBPJARJEY-UHFFFAOYSA-N
SMILES O1C(Br)=CC=C1C(OCC)=O

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
HS Code  2932.19.5100
NFPA 704
1
2 0

Ethyl 5-broMo-2-furoate, 97+% price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical E1285 Ethyl 5-Bromo-2-furancarboxylate >97.0%(GC) 6132-37-2 1g $95 2026-04-30 Buy
TCI Chemical E1285 Ethyl 5-Bromo-2-furancarboxylate >97.0%(GC) 6132-37-2 5g $378 2026-04-30 Buy
Chem-Impex 44457 Ethyl 5-bromo-2-furancarboxylate ≥97%(GC) 6132-37-2 1G $71.41 2026-05-19 Buy
Chem-Impex 44457 Ethyl 5-bromo-2-furancarboxylate ≥97%(GC) 6132-37-2 5G $217.83 2026-05-19 Buy
Synthonix E45937 Ethyl 5-bromofuran-2-carboxylate 97% 6132-37-2 250mg $19 2026-05-06 Buy
Product number Packaging Price Buy
E1285 1g $95 Buy
E1285 5g $378 Buy
44457 1G $71.41 Buy
44457 5G $217.83 Buy
E45937 250mg $19 Buy

Ethyl 5-broMo-2-furoate, 97+% Chemical Properties,Uses,Production

Synthesis

5-Bromofuroic acid

585-70-6

Ethanol

64-17-5

Ethyl 5-broMo-2-furoate, 97+%

6132-37-2

To a stirred suspension of 5-bromo-2-furoic acid (15.0 g, 78.54 mmol) in 225 mL of dichloromethane was slowly added oxalyl chloride followed by a catalytic amount of N,N'-dimethylformamide at room temperature. After 1 hour of reaction, ethanol (20 mL) was added followed by triethylamine (22 mL). The reaction was continued with stirring for 15 hours. Upon completion of the reaction, the mixture was concentrated to dryness under reduced pressure to give a residue. Extraction was carried out with excess hexane and hexane-dichloromethane (3:1, v/v) solvent mixture. The organic phases were combined, filtered and the filtrate was concentrated to give a yellow oil. Finally, the product was dried under high vacuum to give ethyl 5-bromofuran-2-carboxylate 17.2 g in 93% yield.

References

[1] Patent: WO2004/11418, 2004, A1. Location in patent: Page 133
[2] Patent: WO2005/68460, 2005, A1. Location in patent: Page/Page column 314-315
[3] Journal of Materials Chemistry A, 2014, vol. 2, # 18, p. 6589 - 6597
[4] Chemical Communications, 2015, vol. 51, # 15, p. 3166 - 3168
[5] Patent: CN106977476, 2017, A. Location in patent: Paragraph 0106-0108

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Ethyl 5-broMo-2-furoate, 97+% Spectrum

Ethyl 5-broMo-2-furoate, 97+% 2-Furancarboxylic acid, 5-broMo-, ethyl ester Ethyl 5-broMo-2-furoate ethyl 5-broMo-2-furancarboxylate 5-Bromo-2-furancarboxylic Acid Ethyl Ester Ethyl 5-bromofuran-2-carboxylate 6132-37-2
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