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ChemicalBook >> CAS DataBase List >>5-Amino-1-naphthalenesulfonic acid

5-Amino-1-naphthalenesulfonic acid

CAS No.
84-89-9
Chemical Name:
5-Amino-1-naphthalenesulfonic acid
Synonyms
5-AMINONAPHTHALENE-1-SULFONIC ACID;laurentacid;Laurens Acid;LAURENTS ACID;LAURENT'S ACID;1,5-AMINO ACID;LABOTEST-BB LT01138428;5-SULFO-1-NAPHTHYLAMINE;1-AMINO-5-SULFONAPHTHALENE;Laurent Acid(1.5 cleves acid)
CBNumber:
CB7713334
Molecular Formula:
C10H9NO3S
Molecular Weight:
223.25
MDL Number:
MFCD00014315
MOL File:
84-89-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12
Product description Number Pack Size Price
5-Amino-1-naphthalenesulfonic Acid >98.0%(T) A0345 25g $141
1-Aminonaphthalene-5-sulfonic acid 98%(HPLC) T952 100mg $41
1-Aminonaphthalene-5-sulfonic acid 98%(HPLC) T952 1g $93
1-Aminonaphthalene-5-sulfonic acid 98%(HPLC) T952 5g $276
5-Aminonaphthalene-1-sulfonic acid ≥90% AA003M9X 25g $15
More product size

5-Amino-1-naphthalenesulfonic acid Properties

Melting point >300°C
Boiling point 220°C (rough estimate)
Density 1.3588 (rough estimate)
refractive index 1.6500 (estimate)
solubility Aqueous Base (Slightly), DMSO (Slightly)
pka pK1: 3.69 (25°C)
form powder to crystal
color Purple to Dark purple to Dark red
Water Solubility Soluble in hot water.
Merck 14,6404
BRN 2214149
InChI 1S/C10H9NO3S/c11-9-5-1-4-8-7(9)3-2-6-10(8)15(12,13)14/h1-6H,11H2,(H,12,13,14)
InChIKey DQNAQOYOSRJXFZ-UHFFFAOYSA-N
SMILES Nc1cccc2c(cccc12)S(O)(=O)=O
CAS DataBase Reference 84-89-9(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII W70WC365OD
EPA Substance Registry System 1-Naphthalenesulfonic acid, 5-amino- (84-89-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H335-H312-H314-H332-H315-H319
Precautionary statements  P280g-P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P280-P305+P351+P338-P310
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  20/21/22-34
Safety Statements  26-36/37/39-45
RIDADR  UN 2585 8/PG 3
WGK Germany  3
RTECS  QK1270500
TSCA  TSCA listed
HS Code  2921.45.2000
HazardClass  8
PackingGroup  III
Storage Class 8B - Non-combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Dermal
Skin Corr. 1B
REACH Registrations Active
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
1 0

5-Amino-1-naphthalenesulfonic acid price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical A0345 5-Amino-1-naphthalenesulfonic Acid >98.0%(T) 84-89-9 25g $141 2026-04-30 Buy
AK Scientific T952 1-Aminonaphthalene-5-sulfonic acid 98%(HPLC) 84-89-9 100mg $41 2026-06-04 Buy
AK Scientific T952 1-Aminonaphthalene-5-sulfonic acid 98%(HPLC) 84-89-9 1g $93 2026-06-04 Buy
AK Scientific T952 1-Aminonaphthalene-5-sulfonic acid 98%(HPLC) 84-89-9 5g $276 2026-06-04 Buy
aablocks AA003M9X 5-Aminonaphthalene-1-sulfonic acid ≥90% 84-89-9 25g $15 2026-05-28 Buy
Product number Packaging Price Buy
A0345 25g $141 Buy
T952 100mg $41 Buy
T952 1g $93 Buy
T952 5g $276 Buy
AA003M9X 25g $15 Buy

5-Amino-1-naphthalenesulfonic acid Chemical Properties,Uses,Production

Chemical Properties

1-Aminonaphthalene-5-sulfonic acid [84- 89-9]. (5-aminonaphthalene-1-sulfonic acid), Laurent’s acid, L acid, Purpurin acid, C10H9NO3S, Mr 223.24, crystallizes from hot water as needles of the monohydrate. The alkalimetal salts are all readily soluble in water. Bromination yields the 2,4-dibromo derivative, vigorous nitration gives 2,4-dinitro-1- hydroxynaphthalene, and sulfonation results in 1-aminonaphthalene-2,5,7-trisulfonic acid. 1- Hydroxynaphthalene-5-sulfonic acid is obtained by heating 104 with aqueous bisulfite (reverseBucherer reaction) or via the diazo compound. Caustic fusion produces 5-amino-1-hydroxynaphthalene. Coupling with diazo compounds takes place in the 2-position.

Uses

5-Aminonaphthalene-1-sulfonic acid is an deriva- tizing agents in the precolumn derivatization of some chiral phenoxy acid. Cu(II) based on a dansyl derivative was synthesized with 29.2% overall yield by a seven-step synthetic procedure from the readily available starting material 5-aminonaphthalene-1-sulfonic acid.

Uses

Intermediate of dyestuff

Definition

ChEBI: 5-Amino-1-naphthalenesulfonic acid is a naphthalenesulfonic acid.

Production Methods

Laurent’s acid is coproduced with Peri acid as the minor component of a 5:2 isolated product ratio.

Purification Methods

Crystallise the acid under nitrogen from boiling water and dry it in a steam oven [Bryson Trans Faraday Soc 47 522, 527 1951]. [Beilstein 14 IV 2800.]

91-20-3
84-89-9
Synthesis of 5-Amino-1-naphthalenesulfonic acid from Naphthalene
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View Lastest Price from 5-Amino-1-naphthalenesulfonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-Amino-1-naphthalenesulfonic acid pictures 2026-07-24 5-Amino-1-naphthalenesulfonic acid
84-89-9
1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
5-Amino-1-naphthalenesulfonic acid pictures 2026-05-22 5-Amino-1-naphthalenesulfonic acid
84-89-9
1G/KG 99% 10000000KG Anhuyan (Hainan) Biotechnology Co., LTD
5-Amino-1-naphthalenesulfonic acid pictures 2026-05-22 5-Amino-1-naphthalenesulfonic acid
84-89-9
1G/KG 99% 100MT Anhuyan (Hainan) Biotechnology Co., LTD
5-amino-1-naphthalenesulfonicaci 1-NAPHTHYLAMINE-5-SULFONICACID(LAURENT''SACID) Laurens Acid Laurents acid~1-Naphthylamine-5-sulphonic acid 1-Amino-5-naphthalenesulfonic acid 1-Aminonaphtalene-5-sulfonic acid, 97%+ 5-Aminonaphthalene-1-sulfonic acid, tech. 90% Laurent's Acid 1-Naphthylamine-5-sulfonic Acid Laurent Acid(1.5 cleves acid) laurentacid 5-AMINO-1-NAPHTHALENESULFONIC ACID 5-AMINONAPHTHALENE-1-SULPHONIC ACID LABOTEST-BB LT01138428 LAURENTS ACID LAURENT'S ACID 1-NAPHTHYLAMINE-5-SULFONIC ACID 1,5-AMINO ACID 1-AMINONAPHTHALENE-5-SULFONIC ACID 1-AMINO-5-SULFONAPHTHALENE 5-SULFO-1-NAPHTHYLAMINE 1-aminonaphtalene-5-sulfonicacid 5-AMino-1-naphthalenesulfonic Acid , 98.0%(T) 5-AMino-1-naphthalenesulfonic acid technical, >=90% (T) 1-Naphthalenesulfonic acid, 5-amino- 5-Amino-1-naphthalenesulfonic Acid > 5-Aminonaphthalene-1-sulfonicaci 5-Amino-1-naphthalenesulfonic acid ISO 9001:2015 REACH 5-Aminonaphthalene-1-Sulphonic Acid pure, 90% 5-Amino-1-naphthalenesulfonic Acid, ≥ 98.0% 1-NAPHTHYLAMINE-5-SULPHONIC ACID 5-AMINONAPHTHALENE-1-SULFONIC ACID 84-89-9 84-89-2 H2NCd0H6SO3H NH2C10H6SO2H Building Blocks Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds Intermediates of Dyes and Pigments
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