ChemicalBook >> CAS DataBase List >>(S)-H8-BINAP
(S)-H8-BINAP
- CAS No.
- 139139-93-8
- Chemical Name:
- (S)-H8-BINAP
- Synonyms
- (S)-H8-BINAP;(S)-H8-BINAP technical grade;(S)-H8-BINAP;(S)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene;(S)-(-)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl;(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl;(R)-2,2'-bis(diphenylphosphaneyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene;(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl(S)-H8-BINAP;(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (R)-H8-BINAP;(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl, (S)-H8-BINAP
- CBNumber:
- CB8511445
- Molecular Formula:
- C44H40P2
- Molecular Weight:
- 630.74
- MDL Number:
- MFCD01630795
- MOL File:
- 139139-93-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-04-24 14:58:24
| Product description | Number | Pack Size | Price |
| (S)-H8-BINAP technical grade | 693014 | 50mg | $101 |
| (S)-H8-BINAP technical grade | 693014 | 100mg | $187 |
| (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (S)-(-)-H?-BINAP | 15-2973 | 50mg | $69 |
| (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (S)-(-)-H?-BINAP | 15-2973 | 250mg | $276 |
| (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (S)-(-)-H8-BINAP | 15-2973 | 50mg | $69 |
| Melting point | 207-208°C |
|---|---|
| Boiling point | 745.6±60.0 °C(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder |
| color | off-white |
| optical activity | -69.1°(C=0.5165 g/100ml Toluene) |
| InChIKey | ANSOKCGDSQQISA-UHFFFAOYSA-N |
| SMILES | C1CCc2c(C1)ccc(P(c3ccccc3)c4ccccc4)c2-c5c6CCCCc6ccc5P(c7ccccc7)c8ccccc8 |
| UNSPSC Code | 12352002 |
| NACRES | NA.22 |
(S)-H8-BINAP price More Price(18)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 693014 | (S)-H8-BINAP technical grade | 139139-93-8 | 50mg | $101 | 2026-04-30 | Buy |
| Sigma-Aldrich | 693014 | (S)-H8-BINAP technical grade | 139139-93-8 | 100mg | $187 | 2026-04-30 | Buy |
| Strem Chemicals | 15-2973 | (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (S)-(-)-H?-BINAP | 139139-93-8 | 50mg | $69 | 2026-04-30 | Buy |
| Strem Chemicals | 15-2973 | (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (S)-(-)-H?-BINAP | 139139-93-8 | 250mg | $276 | 2026-04-30 | Buy |
| Strem Chemicals | 15-2973 | (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (S)-(-)-H8-BINAP | 139139-93-8 | 50mg | $69 | 2024-03-01 | Buy |
(S)-H8-BINAP Chemical Properties,Uses,Production
Reactions
- Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
- The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
- Rhodium catalyzed asymmetric regioselective 1,4-addition of arylboronic acids to 3-substituted maleimides.
- Ligand for palladium-catalyzed enantioselective hydrogenation of substituted indoles.
- Rhodium-catalyzed enantioselective cyclization of γ-alkynylaldehydes with acyl phosphonates.
- Enantioselective synthesis of axially chiral 1-arylisoquinolines by Rh-catalyzed [2+2+2] cycloaddition.
- Enantioselective synthesis of 2,3-disubstituted indolines through Bronsted acid/Pd-complex-promoted tandem reactions.
Uses
(S)-H8-BINAP Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-H8-BINAP Suppliers
Global( 47)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shenzhen Nexcon Pharmatechs Ltd. | +86-0755-89396905 +86-18025329037 | admin@nexconn.com | China | 5615 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 | jiuyitime@fdachem.com | China | 16511 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29812 | 58 |
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 462 | 58 |
| changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9653 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Wuhan Fortuna Chemical Co.,Ltd | +86-2759207851; +8618007136271 | hk@fortunachem.com | China | 6006 | 58 |
| Watson Biotechnology Co.,Ltd | +8618186686046 | sales01@watsonbiotech.cn | China | 5731 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39927 | 58 |
| Xinxiang Runyu Material Co., Ltd. | 166-166-37336996 15690792173 | chenxi.song@runvmat.com | China | 280 | 55 |
View Lastest Price from (S)-H8-BINAP manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-07-24 | (S)-H8-BINAP
139139-93-8
|
1KG | 99% | 2000 | Shenzhen Nexcon Pharmatechs Ltd. | ||
 |
2026-07-02 | (S)-H8-BINAP
139139-93-8
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2025-12-23 | (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6', 7,7',8,8'-octahydro-1,1'-binaphthyl;(S)-H8-BINAP
139139-93-8
|
1g | 98%+ | 500 | XINXIANG RUNYU MATERIAL CO., LTD. |
-
- (S)-H8-BINAP
139139-93-8
- 99%
- Shenzhen Nexcon Pharmatechs Ltd.
-
- (S)-H8-BINAP
139139-93-8
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- (S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6', 7,7',8,8'-octahydro-1,1'-binaphthyl;(S)-H8-BINAP
139139-93-8
- 98%+
- XINXIANG RUNYU MATERIAL CO., LTD.
139139-93-8((S)-H8-BINAP)Related Search:
(R)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole
(R)-DTBM-SEGPHOS
(R)-DM-BINAP
(S)-SunPhos
(S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-(+)-TolBINAP
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
1of4
(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl
(S)-H8-BINAP technical grade
(S)-H8-BINAP
(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl(S)-H8-BINAP
[(1S)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-[1,1μ-binaphthalene]-2,2μ-diyl]bis[diphenylphosphine], (S)-(-)-2,2μ-Bis(diphenylphospino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl
(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl (R)-H8-BINAP
(S)-(-)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl
(S)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene
Phosphine, 1,1'-[(1S)-5,5',6,6',7,7',8,8'-octahydro[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-diphenyl-
(S)-(-)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl, (S)-H8-BINAP
(S)-H8-BINAP
(R)-2,2'-bis(diphenylphosphaneyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene
139139-93-8
BINAP Series
Chiral Phosphine
