(+)-リモネン 化學(xué)特性,用途語,生産方法
外観
無色～わずかにうすい黃色, 澄明の液體
定義
本品は、次の化學(xué)式で表されるテルペンである。
溶解性
水に不溶, エタノール, アセトンに易溶。エタノール及びアセトンに溶けやすく、水にほとんど溶けない。
無機(jī)性値/有機(jī)性値
14/190
用途
香料
用途
病理組織標(biāo)本作成時の中間剤。
用途
香料原料
化粧品の成分用途
溶剤、香料
効能
香料
使用上の注意
空気と光を避けておけば比較的安定であるが、さもないと酸化されやすい。
説明
d-Limonene has a pleasant, lemon-like odors free from campho raceous and turpentine-like. d-Limonene may be obtained by
steam distillation of citrus peels and pulp resulting from the pro duction of juice and cold-pressed oils, or from deterpenation of
citrus oils; it is sometimes redistilled.
The most important and widespread terpene; it is known in the el and I- optically active forms and in the optically inactive dl-form
(known as dipentene); it has been reported found in more than 300
essential oils in amounts ranging from 90 - 95% (lemon, orange,
mandarin) to as low as 1% (palmarosa);1 the most widespread form
is the d-limonene, followed by the racemic form, and then ι-
limonene.
化學(xué)的特性
colourless liquid
天然物の起源
It has been reported found in more than 300 essential oils in amounts ranging from 90 to 95% (lemon, orange,
mandarin) to as low as 1% (palmarosa); the most widespread form is the d-limonene, followed by the racemic form and then l-limo nene. Also reported found in ginger, nutmeg, pepper, mace, hop oil, coriander seed, calamus, dill herb, caraway seed and rosemary.
使用
Chiral building block. Biodegradable solvent. Limonene is used as a solvent for filament-fused 3D printing, in cosmetic products, as a fragrance and as a biofuel. It is useful to promote weight loss, prevent cancer, treat cancer and treat bronchitis. It also finds use in foods, beverages, chewing gum, as a flavoring agent and a shrinking agent to dissolve polystyrene. It acts as a chiral intermediate for natural product synthesis.
製造方法
d-Limonene may be obtained by steam distillation of citrus peels and pulp resulting from the production of juice and cold pressed oils, or from deterpenation of citrus oils; it is sometimes redistilled.
定義
ChEBI: An optically active form of limonene having (4R)-configuration.
一般的な説明
Clear colorless mobile liquid with a pleasant lemon-like odor.
空気と水の反応
Highly flammable. Insoluble in water.
反応プロフィール
(+)-Dipentene is sensitive to exposure to light. Atmospheric oxidation can occur. (+)-Dipentene is incompatible with strong oxidizing agents. (+)-Dipentene reacts violently with (iodine pentafluoride + tetrafluoroethylene). With dry hydrogen chloride or hydrogen bromide, (+)-Dipentene forms monohalides. With aqueous hydrogen chloride or hydrogen bromide, (+)-Dipentene forms the dihalide.
火災(zāi)危険
(+)-Dipentene is combustible.
農(nóng)業(yè)用途
Insecticide, Animal and insect repellant, Slimicide: Used as an insecticide, insect repellent, and animal
repellent. Not listed for use in EU countries. Registered
for use in the U.S., Canada and other countries. There are
49 global suppliers.
製品名
BUGAWAY®[C]; BUGCHASER®[C];
CARVENE®; DOO-NOT®; HOLIDAY FIRE ANT
KILLER®
接觸アレルゲン
d-Limonene is contained in Citrus species such as citrus,
orange, mandarin, and bergamot. d-limonene, used
as a solvent, may be found in cleansing or in degreasing
agents. Its sensitizing potential increases with prolonged
air contact, which induces oxidation and leads
to oxidation products. The presence of d-limonene has
to be mentioned by name in cosmetics of the EU.
(+)-リモネン 上流と下流の製品情報
原材料
準(zhǔn)備製品
(R)-(-)-カルボン
2-メチル-5-イソプロペニルシクロヘキサノン
(-)-p-メンタ-6(1),8-ジエン-2-オール
p-シメン
2,6-ジメチル-2,4,6-オクタトリエン
2-Cyclohexen-1-ol, 2-methyl-5-(1-methylethenyl)-, (5R)-
(1R-TRANS) 1-METHYL-4-(1-METHYLETHENYL)-2-CYCLOHEXENE-1-OL
1-メチル-4-イソプロペニル-1,2-エポキシシクロヘキサン
(1S,4R)-1-メチル-4-(1-メチルエテニル)-2-シクロヘキセン-1-オール
p-メンタ-1(7),8(10)-ジエン-9-オール
(4β)-p-メンタ-1(7),8-ジエン
(5S,6E)-5-イソプロピル-8-メチル-6,8-ノナジエン-2-オン
2,6,6-トリメチル-2,4-シクロヘプタジエン-1-オン
(4R)-1,2-エポキシ-4-(2-メチルオキシラニル)-1-メチルシクロヘキサン