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I-?????????? ??
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- 75 °C(lit.)
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- 0.733 g/mL at 25 °C(lit.)
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- n
20/D 1.371(lit.)
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- 69 °F
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- 2-8°C
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- Specific Gravity
- 0.7596
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- InChI
- 1S/C4H7N/c1-4(2)5-3/h4H,1-2H3
- InChIKey
- MJZUMMKYWBNKIP-UHFFFAOYSA-N
- SMILES
- CC(C)[N+]#[C-]
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- ?? ? ???? ?? (GHS)
| ??? ?? | F,T | ||
|---|---|---|---|
| ?? ???? ?? | 11-23/24/25 | ||
| ????? | 16-23-26-33-36/37/39-45 | ||
| ????(UN No.) | UN 1992 3/PG 2 | ||
| WGK ?? | 3 | ||
| ?? ?? | 3, 6.1 | ||
| ???? ??? | 3 - Flammable liquids | ||
| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Flam. Liq. 2 |
| ????(GHS): |
 
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| ?? ?: | Danger | ||||||||||||||
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Isopropyl isocyanide may be used in the preparation of:- Ugi ligand A2C11I1, which is employed in the solid-phase Ugi synthesis.
- Pentafluorophenyl (PFP) functional monomers, via Passerini reaction.
- Dinuclear copper complex [Cu2(μ-PiPr2bipy)2{μ-CNCH(CH3)2}](PF6)2 [PiPr2bipy = 6-(diisopropylphosphanyl)-2,2′-bipyridine].
- (3E)-(Imino)thiaisoindoline 1,1-dioxide derivative.
- N,N′-diisopropylcarbodiimide (DIC) analog via reaction with propan-2-amine.
- 1-t-butyl-2-isopropyldiaziridinone via reaction with 2-methyl-2-nitrosopropane
- isopropyl isocyanate via reaction with ozone
- 1-phthalimidoazetidines via [1+3]cycloaddition reaction with 1-pththalimidoaziridines
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To a flask containing 100 ml (0.85 mole) of distilled quinoline is added with stirring 41 gm (0.214 mole) of /7-toluenesulfonyl chloride (see Note), and the solution is warmed to 75°C. Then 18.4 gm (0.212 mole) of isopropylformamide is added and the pressure of the system is reduced to 70 mm Hg. The isopropylisonitrile as it forms distills into a liquid nitrogencooled receiver. (Dry ice is not as effective but may be used.) The product is redistilled to afford 4.2 gm (30%), b.p. 88-89°C (735 mm Hg).
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Isopropyl isocyanide is an alkyl isocyanide.I-?????????? ?? ?? ? ???
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I-?????????? ?? ??:
I-PROPYLISOCYANIDE
CYCLOPENTYL ISOCYANIDE
1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE
TERT-BUTYL ISOCYANIDE
CYCLOHEXYL ISOCYANIDE
(1-Isocyanoethyl)benzene
TERT-AMYLISOCYANIDE
aerocyanidin
1-ADAMANTANEISOCYANIDE
TRIPHENYLMETHYLISOCYANIDE
DIPHENYLMETHYL ISOCYANIDE
3-(N-BUTOXYCARBONYLAMINO)PROPYLISOCYANIDE,3-(N-T-BUTOXYCARBONYLAMINO)PROPYLISOCYANIDE,3-(N-TERT-BUTOXYCARBONYLAMINO)PROPYLISOCYANIDE
2-ISOCYANOBUTANE
1-METHYL-3-PHENYLPROPYLISOCYANIDE
ETHYL 2-ISOCYANO-2-METHYLPROPANOATE
2-PENTYL ISOCYANIDE
3-ISOCYANOOCTANE
CYCLOOCTYLISOCYANIDE