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2-???????????-2',6'-??(??????)-1,1'-????

2-???????????-2',6'-??(??????)-1,1'-????
2-???????????-2',6'-??(??????)-1,1'-???? ??? ???
?? ??:
1160556-64-8
???:
2-???????????-2',6'-??(??????)-1,1'-????
???(??):
2-???????????-2',6'-??(??????)-1,1'-????
???:
CPhos
???(??):
Cphos;2-Dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl;2-(Dicyanomethylen)indan;phosphino-2',6'-bis(N,N-dimethyL;2’-(Dicyclohexylphosphino)-2,6-di(dimethylamino)biphenyl;2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHYLAMINO-1,1'-BIPHENYL;2-Dicyclohexylphosphino-2',6'-bis(N,N-dimethylamino)biphenyl;2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-bipheny;2'-(Dicyclohexylphosphino)-N2,N2,N6,N6-tetramethyl[1,1'-biphen;2'-(dicyclohexylphosphino)-N2,N2,N6,N6-tetramethylbiphenyl-2...
CBNumber:
CB02709536
???:
C28H41N2P
??? ??:
436.61
MOL ??:
1160556-64-8.mol
MSDS ??:
SDS

2-???????????-2',6'-??(??????)-1,1'-???? ??

???
111-113°C
?? ?
592.8±50.0 °C(Predicted)
?? ??
Inert atmosphere,Room Temperature
???
?????(?? ???), ???(?? ???)
?? ?? (pKa)
5.04±0.28(Predicted)
??? ??
?? ??
??
???-???
InChI
InChI=1S/C28H41N2P/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23/h11-13,18-23H,5-10,14-17H2,1-4H3
InChIKey
DRNAQRXLOSUHBQ-UHFFFAOYSA-N
SMILES
C1(C2=CC=CC=C2P(C2CCCCC2)C2CCCCC2)=C(N(C)C)C=CC=C1N(C)C
CAS ??????
1160556-64-8
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26
WGK ?? 3
???? ??? 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

2-???????????-2',6'-??(??????)-1,1'-???? C??? ??, ??, ??

??

CPhos, the full name of which is 2'-(Dicyclohexylphosphino)-N2,N2,N6,N6-tetramethyl(1,1'-biphenyl)-2,6-diamine, is a highly efficient palladium catalyst with excellent cross-coupling activity and is widely used in organic synthesis and materials science.

??

CPhos, is used as a catalyst in the synthetic preparation of palladium-catalyzed Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides.

2-???????????-2',6'-??(??????)-1,1'-???? ?? ?? ? ???

???

?? ??


2-???????????-2',6'-??(??????)-1,1'-???? ?? ??

???( 115)?? ??
??? ?? ??? ?? ?? ? ??
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2-???????????-2',6'-??(??????)-1,1'-???? ?? ??:

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