ChemicalBook >?? ???? >(2R)-(-)-????4-????????
(2R)-(-)-????4-????????
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(2R)-(-)-????4-???????? ??
- ???
- 60-62 °C (lit.)
- ?? ??
- 2-8°C
- ??? ??
- solid
- ?? ??
- [α]19/D 37°, c = 1.08 in chloroform
- BRN
- 5278590
- InChI
- 1S/C10H9NO5/c12-10(16-6-9-5-15-9)7-1-3-8(4-2-7)11(13)14/h1-4,9H,5-6H2/t9-/m1/s1
- InChIKey
- MUWIANZPEBMVHH-SECBINFHSA-N
- SMILES
- [O-][N+](=O)c1ccc(cc1)C(=O)OC[C@H]2CO2
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- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36 | ||
| WGK ?? | 3 | ||
| RTECS ?? | RR0511000 | ||
| F ?????? | 10-21 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| ????(GHS): |
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| ?? ?: | Warning | ||||||||||||||||||||||||||||
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(2R)-(-)-????4-???????? C??? ??, ??, ??
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(2R)-()-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.Purification Methods
Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.](2R)-(-)-????4-???????? ?? ?? ? ???
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(2R)-(-)-????4-???????? ?? ??
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(2R)-(-)-????4-???????? ?? ??:
(R)-(-)-???? ?? ??? p-????????????? ????????????? 4-??????? 4-????????
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(S)-Oxiranemethanol
BENZYL GLYCIDYL ETHER
3-Benzyloxy-1-propanol
4-(METHOXYMETHYL)ANILINE
(S)-(-)-Propylene oxide
Methyl 4-nitrobenzoate
(S)-(+)-GLYCIDYL-4-NITROBENZOATE,(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
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