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?? ??:
2423-65-6
???:
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???(??):
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???:
PYRAZINE N-OXIDE
???(??):
Pyrazine-1-oxide;PYRAZINE N-OXIDE;RARECHEM BG FB 0041;Pyrazine N-oxide 97%;1-oxidopyrazin-1-ium;Pyrazine N-oxide
CBNumber:
CB2470485
???:
C4H4N2O
??? ??:
96.09
MOL ??:
2423-65-6.mol

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???
112-116 °C
?? ?
126-127 °C(Press: 14 Torr)
??
1.19±0.1 g/cm3(Predicted)
?? ??
under inert gas (nitrogen or Argon) at 2-8°C
??? ??
solid
?? ?? (pKa)
0.45±0.39(Predicted)
??
Light yellow to yellow Solid
InChI
1S/C4H4N2O/c7-6-3-1-5-2-4-6/h1-4H
InChIKey
RUIZBQQGWNBRFH-UHFFFAOYSA-N
SMILES
[O-][n+]1ccncc1
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xn
?? ???? ?? 11-22-37/38-41
????? 26-39
????(UN No.) UN 1325 4.1/PG 2
WGK ?? 3
???? ??? 4.1B - Flammable solid hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Flam. Sol. 1
Skin Irrit. 2
STOT SE 3
????(GHS): Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H228 ??? ?? ??? ?? ?? 1
?? 2
??
??
P210, P240,P241, P280, P370+P378
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H318 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 1 ?? P280, P305+P351+P338, P310
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P210 ?·???·??·????? ????? - ?? ???.
P240 ??? ????? ?? ? ??????.
P280 ????/???/???/?????? ?????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

???N-???? C??? ??, ??, ??

Purification Methods

If the sample contains pyrazine-1-oxide, then place it in a Soxhlet extractor and extract it with hot pet ether (b 60-68o) in which the mono-oxide is soluble. Collect the dioxide from the thimble and recrystallise it from MeOH. It is dried in vacuo. It has at 1270cm-1 . [Koelsch & Gumprecht J Org Chem 23 1605 1958.]

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