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1,3-Bis(N-carbazolyl)benzene

1,3-Bis(N-carbazolyl)benzene ??? ???
?? ??:
550378-78-4
???:
1,3-Bis(N-carbazolyl)benzene
???(??):
1,3-di(9H-carbazol-9-yl)benzene;9,9'9,9´9,9'-(1,3-Phenylene);1,3-Di(9H-carbazol-9-yl);1,3-Di-9-carbazolylbenzene;1,3-Bi(carbazol-9-yl)benzene;1,3-Bis(N-carbazolyl)benzene;1,3-bis(9-carbazolyl)benzene;N,N'-Dicarbazolyl-3,5-benzene
CBNumber:
CB31089412
???:
C30H20N2
??? ??:
408.49
MOL ??:
550378-78-4.mol
MSDS ??:
SDS

1,3-Bis(N-carbazolyl)benzene ??

???
176-178°C
?? ?
644.2±51.0 °C(Predicted)
??
1.21
?? ??
Sealed in dry,Room Temperature
??? ??
powder to crystal
??
???? ?? ??
?? ??(λmax)
292338 nm
InChI
InChI=1S/C30H20N2/c1-5-16-27-23(12-1)24-13-2-6-17-28(24)31(27)21-10-9-11-22(20-21)32-29-18-7-3-14-25(29)26-15-4-8-19-30(26)32/h1-20H
InChIKey
MZYDBGLUVPLRKR-UHFFFAOYSA-N
SMILES
C1(N2C3=C(C=CC=C3)C3=C2C=CC=C3)=CC=CC(N2C3=C(C=CC=C3)C3=C2C=CC=C3)=C1
Absorption
λmax 292, 338 nm (in THF)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 37/38-41
????? 26-36/37/39-41-37/38
WGK ?? 3
HS ?? 29339900
???? ??? 11 - Combustible Solids
Hazard Classifications Eye Dam. 1
Skin Irrit. 2
STOT SE 3
????(GHS): Corrosion (GHS05)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H318 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 1 ?? P280, P305+P351+P338, P310
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
NFPA 704
0
2 0

1,3-Bis(N-carbazolyl)benzene C??? ??, ??, ??

??

1,3-Bis(N-carbazolyl)benzene, known as mCP, with a high triplet energy (ET = 2.91 eV) and a very deep highest occupiedmolecular orbital (HOMO) level, is often used as host materials for efficient blue phosphorescent light-emitting diodes. Kawamura et al. demonstrated that the photoluminescence internal quantum yield of the blue emitter of FIrpic could approach nearly 100% when doped into the wide energy gap host of mCP .

??

9,9'-(1,3-Phenylene)bis-9H-carbazole uses as a phosphorescent host material

?? ??

[1] JUAN MENTADO-MORALES. A Promising Thermodynamic Study of Hole Transport Materials to Develop Solar Cells: 1,3-Bis(N-carbazolyl)benzene and 1,4-Bis(diphenylamino)benzene.[J]. Molecules, 2022. DOI:10.3390/molecules27020381.
[2] DAE-KYU KIM; Jong H C; Yoo Lim Kim. Organic Light-Emitting Transistors Based on Pentacene and 4,5-Di(9H-carbazol-9-yl)phthalonitrile Doped onto 1,3-Bis(N-carbazolyl)benzene[J]. The Journal of Physical Chemistry C, 2019. DOI:10.1021/acs.jpcc.9b00150.

1,3-Bis(N-carbazolyl)benzene ?? ?? ? ???

???

?? ??


1,3-Bis(N-carbazolyl)benzene ?? ??

???( 172)?? ??
??? ?? ??? ?? ?? ? ??
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1,3-Bis(N-carbazolyl)benzene ?? ??:

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