ChemicalBook >?? ???? >?? ??>?? ??>?? ? ???>(S)-7,7'-??[?(p-????)????]-1,1'-?????

(S)-7,7'-??[?(p-????)????]-1,1'-?????

(S)-7,7'-??[?(p-????)????]-1,1'-????? ??? ???

?? ??:: 817176-80-0

???:: (S)-7,7'-??[?(p-????)????]-1,1'-?????

???(??):: (S)-7,7'-??[?(p-????)????]-1,1'-?????

???:: (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%

???(??):: (S)-Tol-SDP;(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%;(S)-7,7'-Bis(di-p-tolylphosphanyl)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene];(S)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine);(S)-7,7'-bis[di(4-methylphenyl)phosphanyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[indene;(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;1,1'-[(1S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)phosphine;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE];Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-

CBNumber:: CB32129579

???:: C45H42P2

??? ??:: 644.76

MOL ??:: 817176-80-0.mol

?? ?? 32

(S)-7,7'-??[?(p-????)????]-1,1'-????? ??

???: 150-152°C

??: -221° (c 0.54, CH2Cl2)

?? ?: 722.0±60.0 °C(Predicted)

?? ??: -20°C

??? ??: ??

??? ??: ??? ??

??: ???

?? ??: [α]22/D 206°, c = 1 in chloroform

??: air sensitive

InChIKey: VLIOMJFCGWZUON-UHFFFAOYSA-N

SMILES: Cc1ccc(cc1)P(c2ccc(C)cc2)c3cccc4CCC5(CCc6cccc(P(c7ccc(C)cc7)c8ccc(C)cc8)c56)c34

?? ? ?? ??
?? ? ???? ?? (GHS)

WGK ??	3
???? ???	13 - Non Combustible Solids

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H302	??? ???	?? ?? ?? - ??	?? 4	??	P264, P270, P301+P312, P330, P501
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

(S)-7,7'-??[?(p-????)????]-1,1'-????? C??? ??, ??, ??

(S)-7,7'-??[?(p-????)????]-1,1'-????? ?? ?? ? ???

???

???? ??? (II) ???? 1,4- ?? (? ?? ?? ??) ?? ?? ??? ????? ??? ???????????? ??????? ??? ?????????????? 4-?????? ????????? ???? ???????? ?? ??????(??) ?????? ???? ????? ?????? ??? ?? ??? ???? (S)-1,1'-SPIROBIINDANE-7,7'-DIOL ???

?? ??

(S)-7,7'-??[?(p-????)????]-1,1'-????? ?? ??

???( 32)?? ??

???	??	???	??	?? ?	??
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	904	58
Zhuoer Chemical Co., Ltd	02120970332; +8613524231522	sales@zhuoerchem.com	China	2904	58
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J & K SCIENTIFIC LTD.	18210857532; 18210857532	jkinfo@jkchemical.com	China	96815	76
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44816	61
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	7676	65
Bide Pharmatech Ltd.	400-400-164-7117 18317119277	product02@bidepharm.com	China	40000	60
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51395	80
Shanghai Chiral bio-compound co., Ltd.	021-5068 3667/17749785980/1029026415; 17749785980	1029026415@qq.com	China	4359	58
Shanghai YuanYe Biotechnology Co., Ltd.	021-61312847; 18021002903	3008007409@qq.com	China	89686	60

(S)-7,7'-??[?(p-????)????]-1,1'-????? ?? ??:

(R)-N-((3-Methylpyridin-2-yl)methyl)-7′-di(3,5-di-tert-butylphenyl)phosphino-1,1′-spirobiindanyl-7-amine (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 2-Pyridinemethanamine, N-[(1aS,4aS,9bS)-10-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-1a,2,3,4,4a,5-hexahydro-1H-indeno[2,1-d]fluoren-9-yl]-3-methyl- 2-Pyridinemethanamine, N-[(1S)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl- (S)-DTB-SpiroSAP

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