2-???????
|
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2-??????? ??
- ???
- 122-125 °C (lit.)
- ?? ?
- 114 °C
- ??
- 1,46 g/cm3
- ?? ??
- Sealed in dry,Room Temperature
- ???
- 7.2g/L
- ??? ??
- ??? ?? ?? ??
- ?? ?? (pKa)
- 3.27(at 25℃)
- ??
- ???? ?? ???
- ???
- ?? ?? ?????.
- BRN
- 971265
- InChI
- InChI=1S/C7H5FO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10)
- InChIKey
- NSTREUWFTAOOKS-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=CC=CC=C1F
- CAS ??????
- 445-29-4(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 37/38-36/37/38 | ||
| ????? | 22-26-28-24/25-37/39-36 | ||
| WGK ?? | 3 | ||
| RTECS ?? | DH0250000 | ||
| TSCA | TSCA listed | ||
| ?? ?? | IRRITANT | ||
| HS ?? | 29163900 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 |
2-??????? C??? ??, ??, ??
??? ??
white to light yellow crystal powder. soluble in organic solvents such as benzene, toluene, ketone and ether.The corresponding 2-fluorobenzoyl chloride can be obtained by reacting 2-fluorobenzoic acid with an acid chloride agent such as SOCl2, PCl3, etc.??
2-Fluorobenzoic acid may be employed in the preparation of zaragozic acid A analogs. It is also used as an organic chemical synthesis intermediate.??
2-Fluorobenzoic acid is an intermediate of the fungicide tritriazole and meclofenamic acid.??
ChEBI: 2-fluorobenzoic acid is a 2-halobenzoic acid that is benzoic acid carrying a fluoro substituent at position 2. It is a fluorobenzoic acid and a 2-halobenzoic acid. It is a conjugate acid of a 2-fluorobenzoate.?? ??
The preparation of 2-fluorobenzoic acid is based on anthranilic acid as raw material, adding anhydrous hydrogen fluoride and sodium nitrite in methoxyethyl methyl ether solvent for diazotization, refluxing for 3 hours, and post-processing to obtain the finished product.Purification Methods
Crystallise the acid from 50% aqueous EtOH, dilute HCl or *C6H6, then purify it by zone melting or vacuum sublimation at 130-140o. [Beilstein 9 H 333. 9 III 1324, 9 IV 950.]2-??????? ?? ?? ? ???
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2-??????? ?? ??
???( 563)?? ??
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