(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
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(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ??
- ???
- 20 °C(lit.)
- ?? ?
- 73-76 °C9 mm Hg(lit.)
- ??
- 1.300 g/mL at 20 °C(lit.)
- ???
- n
20/D 1.459(lit.)
- ???
- 189 °F
- ?? ??
- Keep in dark place,Inert atmosphere,Room temperature
- ?? ?? (pKa)
- 11.91±0.10(Predicted)
- ??? ??
- ??? ??
- ??
- ?? ?? ?? ??
- ?? ??
- -32.968°(C=0.01gml DCM)
- CAS ??????
- 10531-50-7(CAS DataBase Reference)
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- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi,C | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-36 | ||
| ????(UN No.) | NA 1993 / PGIII | ||
| WGK ?? | 3 | ||
| F ?????? | 10-23 | ||
| HS ?? | 29062990 |
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL C??? ??, ??, ??
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(R)-2,2,2-Trifluoro-1-phenylethanol is a building block used in the synthesis of mesoporous metal-organic frameworks.Purification Methods
Purify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.](R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ?? ?? ? ???
???
Benzene, [2,2,2-trifluoro-1-[(trimethylsilyl)oxy]ethyl]-
4,4,4-trifluoro-3-hydroxy-1,3-diphenyl-1-butanone
(S)-(-)-1-PHENYLETHANOL
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
Trifluoroacetophenone
(S)-(+)-Methyl mandelate
(R)-(-)-Methyl mandelate
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?? ??
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ?? ??
???( 97)?? ??
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(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL ?? ??:
1-??-2,2,2-????????? ?????????
4-(2-HYDROXYHEXAFLUOROISOPROPYL)BENZOIC ACID
(S)-(+)-ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETYL CHLORIDE
1,4-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE
(S)-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetic acid
1,3-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE
(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL
4-(HEXAFLUORO-2-HYDROXYISOPROPYL)ANILINE
HEXAFLUORO-2-(P-TOLYL)ISOPROPANOL
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
1-PHENYL-2,2,2-TRIFLUOROETHANOL
4-CHLORO-(2-HYDROXYHEXAFLUOROISOPROPYL)BENZENE
BIS(4-FLUOROPHENYL)TRIFLUOROMETHYL CARBINOL
BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR
4,4'-BIS(2-HYDROXYHEXAFLUOROISOPROPYL)BIPHENYL
2-(2,5-Dimethylphenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol
ALPHA-(TRIFLUOROMETHYL)BENZHYDROL