????(1,5-??????)????(II)
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????(1,5-??????)????(II) ??
- ???
- 210 °C (dec.) (lit.)
- ?? ??
- Inert atmosphere,Room Temperature
- ???
- ??????? ???
- ??? ??
- ?? ??
- ??
- ???
- ???
- ???
- ??
- Hygroscopic
- InChI
- InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
- InChIKey
- NEKYMUKEOUDFPP-XRGHXPOKSA-L
- SMILES
- C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|
- CAS ??????
- 12107-56-1(CAS DataBase Reference)
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- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 26-37/39 | ||
| WGK ?? | 3 | ||
| TSCA | TSCA listed | ||
| HS ?? | 28439000 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
????(1,5-??????)????(II) C??? ??, ??, ??
??? ??
Dichloro(1,5-cyclooctadiene)palladium(II) is pale yellow to brown, soluble in dichloromethane, and sensitive to air, light, moisture, and heat. It must be filled with an inert gas, sealed, and stored in a dry environment at 2-8°C.??
Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.?? ??
Used in alcohol protection; synthesis of carbamates, bicyclooctanes and alkene carbonylation.????(1,5-??????)????(II) ?? ?? ? ???
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????(1,5-??????)????(II) ?? ??
???( 285)?? ??
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