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???? ??(II)
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1120-44-1
???:
???? ??(II)
???(??):
??????(II);??????(II)
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COPPER(II) OLEATE
???(??):
COPPER OLEATE;Cuprex;Nsc112237;CUPRIC OLEATE;copperdioleate;copper(2++)salt;COPPER(II) OLEATE;Oleic acid copper;copper oleate(1120-44-1);COPPERCIS-9-OCTADECENOATE
CBNumber:
CB6174813
???:
C18H34CuO2
??? ??:
346.01
MOL ??:
1120-44-1.mol
MSDS ??:
SDS

???? ??(II) ??

???
100°
?? ?
211.9℃[at 101 325 Pa]
??
971[at 20℃]
???
0.616Pa at 20℃
???
insoluble in H2O; slightly soluble in ethanol; soluble in ethyl ether
??? ??
??? ??
??
??-??
???
??? H2O; ??? ???; ??? ??? [MER06]
Dielectric constant
2.8(20℃)
InChI
InChI=1S/C18H34O2.Cu/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h9-10H,2-8,11-17H2,1H3,(H,19,20);/b10-9-;
InChIKey
XVBODFCHDIQCGK-KVVVOXFISA-N
SMILES
C(CCCCCC(=O)O)C/C=C\CCCCCCCC.[Cu]
LogP
14.74 at 25℃
EPA
Cupric oleate (1120-44-1)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
TSCA TSCA listed
????(GHS): Exclamation Mark (GHS07)Environment (GHS09)
?? ?: Warning
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?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H411 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 2
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P272 ??? ??? ??? ??? ???? ???.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P321 (…) ??? ???.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P333+P313 ????? ?? ??? ???? ???? ??·??? ????.
P362 ??? ??? ?? ?? ?? ?????
P363 ?? ??? ??? ??? ?????.
P501 ...? ??? / ??? ?? ???.

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Copper(II) oleate is a blue to green solid; can be prepared by reacting the acid with CuO or basic carbonate of Cu; coalesces mercury drops; improves oil combustion by reducing smoke and fumes of burning oil; used as textile fungicide, used in antifouling marine paints [MER06].

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In antifouling compositions; as emulsifier and dispersing agent; as antioxidant in lubricating oils; as combustion-improver in fuel oils; as stabilizer for amide polymers; as catalyst.

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Copper(II) oleate is produced by the precipitation reaction of copper(II) sulfate solutions with sodium oleate. It is insoluble in water. The product of commerce contains between 6% and 9% copper. Copper(II) oleate is used as an emulsifier and dispersant for the control of mildew and as a combustion improver in fuel oils.

Purification Methods

Crystallise it from diethyl ether. [Beilstein 2 H 465, 2 I 196, 2 I202, 2 II 436, 2 III 1404, 2 IV 1646.]

Toxicity evaluation

Toxicity of Copper(II) oleate was demonstrate in experiments on S.mansoni cercariae. 1 mL of Copper(II) oleate (20% in ether) was put in a tet tube containing 10 mL of aerated tap water. Test tubes were allowed to stand for 30 minutes with occasional shaking. The water was then poured off and filtered. 1 mL of filtrate from each tube was placed in a separate Syracuse watch glass. Water saturated with copper oleate killed all the cercariae in 30 minutes.

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