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ORANGE I

ORANGE I ??? ???
?? ??:
523-44-4
???:
ORANGE I
???(??):
oranzi;CI 4600;ORANGE1;OrangeⅠ;c.i.150;oranges;OrangeⅠ;ORANGE I;CI 14600;orangeim
CBNumber:
CB7144028
???:
C16H12N2O4S.Na
??? ??:
351.33
MOL ??:
523-44-4.mol
MSDS ??:
SDS

ORANGE I ??

???
260 °C (decomp)
?? ??
Inert atmosphere,Room Temperature
???
DMSO(?? ???), ???(?? ???)
??? ??
??
??? ??
??? ??
?? ?? ??
14600
??
????? ?? ??? ?????
Merck
14,6857
BRN
3826844
IARC
3 (Vol. 8, Sup 7) 1987
EPA
C.I. Acid Orange 20 monosodium salt (523-44-4)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????? 22-24/25
WGK ?? 3
RTECS ?? DB7085000
TSCA TSCA listed
HS ?? 32041200
?? ?? ??? 523-44-4(Hazardous Substances Data)
?? LD50 intraperitoneal in rat: 1gm/kg
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P301+P312 ??? ???? ??? ????(??)? ??? ????.
P302+P352 ??? ??? ??? ?? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

ORANGE I C??? ??, ??, ??

??? ??

Crystalline

?? ??

4-Aminobenzenesulfonic acid diazo, and Naphthalen-1-olcoupling.

Purification Methods

Purify the dye by dissolving it in the minimum volume of H2O, adding, with stirring, a large excess of EtOH. The salt separates as orange needles. It is collected by centrifugation or filtration, washed with absolute EtOH (3x) and Et2O (2x) in the same way and dried in a vacuum desiccator over KOH. The free acid can be recrystallised from EtOH. [Slotta & Franke Chem Ber 64 86 1931, Beilstein 16 H 275, 16 II 117, 16 IV 410.] The purity can be checked by titration with titanium chloride [Klotz J Am Chem Soc 68 2299 1946].

ORANGE I ?? ?? ? ???

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ORANGE I ?? ??

???( 247)?? ??
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ORANGE I ?? ??:

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