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??-??-???? ????
??-??-???? ???? ??? ???
?? ??:
7337-45-3
???:
??-??-???? ????
???(??):
??-??-????????;??-??-????????
???:
Borane tert-butylamine complex
???(??):
TERT-BUTYLAMINE BORANE;BORANE-TERT-BUTYLAMINE COMPLEX;Borane tert-butyL;BORANE-TERT-BUTYLAMINE;DDK314;NSC 114045;amine compL;butylamineborane;T-BUTYLAMINE BORANE;tert-Butylaminebrane
CBNumber:
CB7422984
???:
C4H11BN
??? ??:
83.94784
MOL ??:
7337-45-3.mol
MSDS ??:
SDS

??-??-???? ???? ??

???
98-100 °C (dec.)(lit.)
??
0,87 g/cm3
?? ??
Refrigerator
???
27g/L
??? ??
??
??
???? ?????
???
?(20°C?? 27g/L) ? ???? ?????.
BRN
4134905
InChI
InChI=1S/C4H11N.BH3/c1-4(2,3)5;/h5H2,1-3H3;1H3
InChIKey
GKFJEDWZQZKYHV-UHFFFAOYSA-N
SMILES
N([H])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H].B
EPA
Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- (7337-45-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T
?? ???? ?? 21-25-36/37/38
????? 26-36/37-45
????(UN No.) UN 2811 6.1/PG 3
WGK ?? 3
RTECS ?? EO3900000
F ?????? 9
TSCA TSCA listed
?? ?? 4.1
???? III
HS ?? 29299090
???? ??? 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Oral
Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
???? ?? KE-04194
????(GHS): Skull and Crossbones (GHS06)Environment (GHS09)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H411 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 2
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P301+P310 ???? ?? ????(??)? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
3 0

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white to off-white crystalline powder

??

Borane-tert-butylamine complex is used in stereoselective reduction of a steroidal ketone and for a review of amine boranes as selective reducing and hydroborating agents. It is also used as strong co-reducing agent in the syntheses of copper (I) oxide nanoparticles, diphosphine-protected gold nanocluster and 4-acetoxycinnamyl alcohols.

?? ??

Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:
copper (I) oxide nanoparticles
diphosphine-protected gold nanocluster
4-acetoxycinnamyl alcohols
Reactant involved in:
Non-destructive analyses and conservation treatments of Indian drawings
Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
The formation of σ-borane complexes
Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
Photochemical hydroboration and oxidation of single-walled carbon nanotubes

?? ??

Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.

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