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Borane-2-picoline complex

Borane-2-picoline complex ??? ???
?? ??:
3999-38-0
???:
Borane-2-picoline complex
???(??):
2-picoline borane;Pic-BH3;2-methylpyridine borane;2-Methylpyridine borane complex;Borane-2-picoL;BORANE - 2-PICOLINE COMPLEX;(2-Methylpyridin-1-iuM-1-yl)trihydroborate;orane-2-picoline coMplex;2- methylpyridine -N- borane;2-Methylpyridine - borane (1:1)
CBNumber:
CB3500718
???:
C6H10BN
??? ??:
106.96
MOL ??:
3999-38-0.mol
MSDS ??:
SDS

Borane-2-picoline complex ??

???
48 °C
??
1.297 g/mL at 25 °C
???
100°(212°F)
?? ??
2-8°C
???
Dichloromethane (Sparingly), Ethyl Acetate (Slightly)
??? ??
??
??? ??
??? ??
??
???
???
?? ?????? ?? ????, ???, ????????, ???? ???? ?? ?? ?? ?? ????
??
Moisture Sensitive
InChI
InChI=1S/C6H10BN/c1-6-4-2-3-5-8(6)7/h2-5H,1,7H3
InChIKey
ZMASBEFBIXMNCP-UHFFFAOYSA-N
SMILES
[B+3](N1=CC=CC=C1C)([H-])([H-])[H-]
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xn,Xi
?? ???? ?? 14/15-40-36/37/38-26
????? 36/37-43-26-36/37/38-14/15
????(UN No.) UN 3130 6.1(4.3) / PGII
WGK ?? 3
?? ?? 4.3
???? II
HS ?? 29333990
???? ??? 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Water-react 2
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H261 ?? ??? ?????? ???? ???? ?? ? ??? ?? 2
?? 3
??
??
P231+P232, P280, P370+P378,P402+P404, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P231+P232 ??? ?? ??? ????, ??? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
2 2
W

Borane-2-picoline complex C??? ??, ??, ??

??

Environmentally benign reducing agent. Reactant for: Reductive amination. N-Benzyl-protection of amino acid derivatives by reductive alkylation. Reductive alkoxyamination.

?? ??

2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.

Borane-2-picoline complex ?? ?? ? ???

???

?? ??


Borane-2-picoline complex ?? ??

???( 245)?? ??
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Borane-2-picoline complex ?? ??:

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