?? (?? ?? ?? ?) ?? (Ⅱ) ? ?????
|
|
?? (?? ?? ?? ?) ?? (Ⅱ) ? ????? ??
- ???
- 250 °C (dec.)(lit.)
- ?? ??
- Inert atmosphere,Room Temperature
- ???
- DMSO(?? ???), ???(?? ???)
- ??? ??
- ?? ?? ??
- ??
- ?? ???? ?? ????
- ???
- ???
- ??
- Hygroscopic
- ?? ??
- NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
- InChI
- InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
- InChIKey
- ZBRJXVVKPBZPAN-UHFFFAOYSA-L
- SMILES
- P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl
- CAS ??????
- 14264-16-5(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | T | ||
|---|---|---|---|
| ?? ???? ?? | 45-43-52/53-34-20/21/22 | ||
| ????? | 53-36/37-45-60-36/37/39-26 | ||
| ????(UN No.) | 3260 | ||
| WGK ?? | 3 | ||
| RTECS ?? | QR6170000 | ||
| F ?????? | 21 | ||
| TSCA | TSCA listed | ||
| ?? ?? | 6.1(b) | ||
| ???? | III | ||
| HS ?? | 29310095 | ||
| ???? ??? | 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects |
||
| Hazard Classifications | Aquatic Chronic 3 Carc. 1B Skin Sens. 1 |
?? (?? ?? ?? ?) ?? (Ⅱ) ? ????? C??? ??, ??, ??
??? ??
dark green to dark grey crystals or powder??
Coordination compund.Purification Methods
Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]?? (?? ?? ?? ?) ?? (Ⅱ) ? ????? ?? ?? ? ???
???
?? ??
?? (?? ?? ?? ?) ?? (Ⅱ) ? ????? ?? ??
???( 390)?? ??
| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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