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3,4-????

3,4-????
3,4-???? ??? ???
?? ??:
95-64-7
???:
3,4-????
???(??):
3,4-????
???:
3,4-Dimethylaniline
???(??):
3,4-XYLIDINE;Benzenamine, 3,4-dimethyl-;3,4-Dimethylbenzenamine;ai3-22779;AKOS 91143;3,4-Xylylamine;ASYM-O-XYLIDINE;4-AMINO-O-XYLENE;AKOS BBS-00003673;3,4-DitolueneAmine
CBNumber:
CB8433299
???:
C8H11N
??? ??:
121.18
MOL ??:
95-64-7.mol
MSDS ??:
SDS

3,4-???? ??

???
49-51 °C(lit.)
?? ?
226 °C(lit.)
??
1.076
???
3.72Pa at 25℃
???
1.5135 (estimate)
???
209 °F
?? ??
Store below +30°C.
???
???: 0.1 g/mL, ??
??? ??
??? ?? ?? ??
?? ?? (pKa)
pK1:5.17(+1) (25°C)
??
??? ????? ??, ?????
???
<1g/L(24°C)
Merck
14,10084
BRN
507414
Henry's Law Constant
5.3×100 mol/(m3Pa) at 25℃, Jayasinghe et al. (1992)
InChI
1S/C8H11N/c1-6-3-4-8(9)5-7(6)2/h3-5H,9H2,1-2H3
InChIKey
DOLQYFPDPKPQSS-UHFFFAOYSA-N
SMILES
Cc1ccc(N)cc1C
LogP
1.8 at 25℃
????
5.15 at 25℃
CAS ??????
95-64-7(CAS DataBase Reference)
NIST
Benzenamine, 3,4-dimethyl-(95-64-7)
EPA
3,4-Dimethylaniline (95-64-7)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T,N
?? ???? ?? 23/24/25-33-51/53
????? 28-36/37-45-61-28A
????(UN No.) UN 3452 6.1/PG 2
WGK ?? 2
RTECS ?? ZE9450000
F ?????? 8
TSCA TSCA listed
?? ?? 6.1
???? II
HS ?? 29214910
???? ??? 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Chronic 2
STOT RE 2
?? ?? ??? 95-64-7(Hazardous Substances Data)
????(GHS): Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
H373 ??? ?? ?? ???? ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ? ?? ?? ???? ?? - ?? ?? ?? 2 ?? P260, P314, P501
H411 ??? ??? ?? ????? ??? ?? ????? ?? - ?? ?? 2
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P314 ???? ??? ???? ??·??? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P391 ???? ????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
3 0

3,4-???? MSDS


1-Amino-3,4-dimethylbenzene

3,4-???? C??? ??, ??, ??

??? ??

slightly beige to beige or pink crystalline mass

??

3,4-Dimethylaniline is used to study electron donor-acceptor interaction with DCNQ. It is also used as a fine chemical &organic intermediate.

??

ChEBI: A primary arylamine that is aniline in which the hydrogens at the 3- and 4-positions are replaced by methyl groups. A low-melting, crystalline solid, it is used in the production of vitamin B2, dyes, pesticides and other chemicals.

?? ??

Pale brown crystals or off-white solid.

??? ?? ??

3,4-Dimethylaniline may be sensitive to prolonged exposure to air. Insoluble in water.

?? ???

3,4-Dimethylaniline ignites on contact with fuming nitric acid . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

????

3,4-Dimethylaniline is combustible.

Safety Profile

Suspected carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also other xylidine entries.

Purification Methods

Crystallise it from ligroin and distil it under vacuum. [Beilstein 12 H 1103, 12 IV 2502.]

3,4-???? ?? ?? ? ???

???

?? ??


3,4-???? ?? ??

???( 271)?? ??
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3,4-???? ?? ??:

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