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?? ???? >(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)?????
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)?????
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)????? ??? ???
?? ??:
65012-74-0
???:
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)?????
???(??):
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)?????
???:
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
???(??):
(bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe;bicycloheptadiene(diphenylphosphino)butane rhodium ClO4;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I);(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
CBNumber:
CB8493732
???:
C35H36ClO4P2Rh
??? ??:
720.96
MOL ??:
65012-74-0.mol
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)????? ??
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210 °C (dec.)(lit.)
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sol CH2Cl2, MeOH, THF/MeOH, and H2O/MeOH mixtures; sparingly sol THF; insol Et2O
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Danger
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P- ??
H272 ??? ???? ?; ???
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?? 2
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P210, P220, P221P280, P370+P378,P501
H315 ??? ??? ???
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?? 2
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P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ???
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?? 2A
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P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ??
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?? 3
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P220 ?? ??? ??? ????? ?????.
P261 ??·?·??·???·??·...·????? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)????? C??? ??, ??, ??
Synthesis
Cationic rhodium-chiraphos complexes are usually prepared in situ or from the procedure given below. In reactions employing the various rhodium-chiraphos complexes, the diene ligand is frequently hydrogenated prior to catalysis to afford the active solvated catalyst precursors [RhS2(chiraphos)]+.
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)????? ?? ?? ? ???
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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)????? ?? ??
???( 7)?? ??
China 3
Switzerland 1
United Kingdom 1
United States 2
Global 7
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)????? ?? ??:
![(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE]??(I)?????](CAS/GIF/65012-74-0.gif)
