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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
GMO  Standard  ERM-BF412,  Maize  Bt-11 GMO Standard ERM-BF412, Maize Bt-11
Carbon  Monoxide,  Carbon  Dioxide,  Hydrogen,  Methane  and  Oxygen Carbon Monoxide, Carbon Dioxide, Hydrogen, Methane and Oxygen
ProteinA,  immobilized  on  polyacrylic  beads,  from  Staphylococcus  aureus ProteinA, immobilized on polyacrylic beads, from Staphylococcus aureus
Porcine  muscle  (chloramphenicol  blank) Porcine muscle (chloramphenicol blank)
Liquid  chromatography  column  fittings Liquid chromatography column fittings
Reservoirs  for  LC  columns Reservoirs for LC columns
Freshwater  sediment  (butyltins) Freshwater sediment (butyltins)
Methane  in  helium Methane in helium
Human  pancreatic  Lipase  (recombinant) Human pancreatic Lipase (recombinant)
Glutaraldehyde-O-2,3,4,5,6-PFBHA-Oxime Glutaraldehyde-O-2,3,4,5,6-PFBHA-Oxime 932710-48-0 C19H12F10N2O2
Poly(methyl  methacrylate)  standard  ReadyCal  set  Mp  500-2μ700μ000 Poly(methyl methacrylate) standard ReadyCal set Mp 500-2μ700μ000
EPA  8270  GC-MS  Tuning  Solution  II EPA 8270 GC-MS Tuning Solution II
EPA  625  Base/Neutral  3  in  Methylene  Chloride EPA 625 Base/Neutral 3 in Methylene Chloride
Hay  powder  (elements) Hay powder (elements)
Alkylphenol  Target  Analyte  Mix  solution  for  DIN  EN  ISO  18857-2 Alkylphenol Target Analyte Mix solution for DIN EN ISO 18857-2
Zinc  68Zn  solution  (certified  for  isotope  abundance  ratio) Zinc 68Zn solution (certified for isotope abundance ratio) Zn
Carbon  Monoxide,  Carbon  Dioxide,  Methane,  Ethane,  Ethylene  and  Acetylene Carbon Monoxide, Carbon Dioxide, Methane, Ethane, Ethylene and Acetylene
Oxygen  in  helium Oxygen in helium
(S)-NIFE (S)-NIFE 328406-65-1 C19H20N2O7
CALCIUM ASCORBATE - REFERENCE SPECTRUM CALCIUM ASCORBATE - REFERENCE SPECTRUM
BOVINE EYE (CLENBUTEROL POSITIVE) BOVINE EYE (CLENBUTEROL POSITIVE)
BEECHWOOD (PCP AND PAH) BEECHWOOD (PCP AND PAH)
SEMIVOLATILE ACIDS SURROGATE SPIKE MIX SEMIVOLATILE ACIDS SURROGATE SPIKE MIX
TICARCILLIN IMPURITY A TICARCILLIN IMPURITY A 6933-26-2 C13H12OS
TRIMETHOPRIM IMPURITY B TRIMETHOPRIM IMPURITY B
TRAMADOL IMPURITY A TRAMADOL IMPURITY A C16H25NO2
TYLOSIN PHOSPHATE FOR PEAK IDENTIFICATION TYLOSIN PHOSPHATE FOR PEAK IDENTIFICATION
AQUANAL-PLUS ACCESSORIES AQUANAL-PLUS ACCESSORIES
AQUANAL-PROFESSIONAL AMMONIA NO.2 AQUANAL-PROFESSIONAL AMMONIA NO.2
AQUANAL-PROFESSIONAL SPADNS REAGENT AQUANAL-PROFESSIONAL SPADNS REAGENT
AQUANAL-PROFESSIONAL MANGANESE LR 1 AQUANAL-PROFESSIONAL MANGANESE LR 1
AQUANAL-PROFESSIONAL NICKEL AQUANAL-PROFESSIONAL NICKEL
AQUANAL-PROFESSIONAL VARIO H PHOSPHATE AQUANAL-PROFESSIONAL VARIO H PHOSPHATE
PROGRAMMED TEST MIX PROGRAMMED TEST MIX
EPA 524 CALIBRATION STANDARDS KIT EPA 524 CALIBRATION STANDARDS KIT
PCB KIT 3 PCB KIT 3
ALUMINUM ATOMIC ABSORPTION STANDARD SOLUTION 1,000 ΜG/ML AL IN 1 WT. % HCL (EXACT AL CONCENTRATION ON LABEL) ALUMINUM ATOMIC ABSORPTION STANDARD SOLUTION 1,000 ΜG/ML AL IN 1 WT. % HCL (EXACT AL CONCENTRATION ON LABEL) Al
GERMANIUM ICP/DCP STANDARD SOLUTION GERMANIUM ICP/DCP STANDARD SOLUTION Ge
TUNA FISH TISSUE (AS SPECIES) TUNA FISH TISSUE (AS SPECIES)
MOLECULAR SIEVE UOP TYPE XL-8 1.3 MOLECULAR SIEVE UOP TYPE XL-8 1.3
AFLATOXIN MIX 4 AFLATOXIN MIX 4
CHROMOIONOPHORE II CHROMOIONOPHORE II 136499-31-5 C46H59N3O5
DICYANOCOBYRINIC ACID HEPTAPROPYL ESTER DICYANOCOBYRINIC ACID HEPTAPROPYL ESTER 93441-85-1 C68H101CoN6O14
4-TERT-BUTYL-2,2,14,14-TETRAHOMO-2A,14A, DIOXACALIX[4]ARENE-TETRAACETIC ACID TETRA-TERT-BUTYL ESTER 4-TERT-BUTYL-2,2,14,14-TETRAHOMO-2A,14A, DIOXACALIX[4]ARENE-TETRAACETIC ACID TETRA-TERT-BUTYL ESTER 135463-06-8 C70H100O14
disodium dihydrogen N,N'-1,2-cyclohexanediylbis[N-(carboxylatemethyl)glycinate] disodium dihydrogen N,N'-1,2-cyclohexanediylbis[N-(carboxylatemethyl)glycinate] 5786-78-7 C14H23N2NaO8
white copper(a copper-nickel alloy) white copper(a copper-nickel alloy)
SULFONAZO III, TITRATION INDICATOR FOR S O4 SULFONAZO III, TITRATION INDICATOR FOR S O4 164581-28-6 C22H12N4Na4O14S4
monensin methyl ester monensin methyl ester 28636-21-7 C37H64O11
16-O-METHYL-CAFESTOL 16-O-METHYL-CAFESTOL 108214-28-4 C21H30O3
2(E),6(Z),9(Z),12(Z),15(Z),18(Z),21(Z)-TETRACOSAHEPTAENOIC ACID METHYL ESTER 2(E),6(Z),9(Z),12(Z),15(Z),18(Z),21(Z)-TETRACOSAHEPTAENOIC ACID METHYL ESTER C25H36O2
OCTADECANOIC ACID-13C18 OCTADECANOIC ACID-13C18 287100-83-8 C18H36O2
LC-NH2  Test  Mix LC-NH2 Test Mix
Fly  ash  from  pulverised  coal  (trace  elements) Fly ash from pulverised coal (trace elements)
Protein  Standards  (Micro)  Set  from  human  serum Protein Standards (Micro) Set from human serum
Mead acid methyl ester (5(Z),8(Z),11(Z)-C20:3) Mead acid methyl ester (5(Z),8(Z),11(Z)-C20:3)
CONDUCT-C CONDUCT-C
NifluMic acid-13C6 NifluMic acid-13C6 1325559-33-8 C13H9F3N2O2
Xylazine-D6 Xylazine-D6 1228182-53-3 C12H16N2S
BACOPASIDE I(SH) BACOPASIDE I(SH) 382148-47-2 C46H74O20S
Cefadroxil Related CoMpound I Cefadroxil Related CoMpound I 147103-94-4 C16H17N3O5S
Cefprozil Related CoMpound H Cefprozil Related CoMpound H
Luxabendazole-D3 Luxabendazole-D3 1448346-27-7 C15H12FN3O5S
(±)-Nicotine-d3 (±)-Nicotine-d3 1173021-00-5 C17H17D3N2O3
5-ANOT 5-ANOT 90223-31-7 C8H9N3O3
Ciprofloxacin-D8 hydrochloride hydrate (see Data Sheet) Ciprofloxacin-D8 hydrochloride hydrate (see Data Sheet) 1216659-54-9 C17H11ClD8FN3O3
KetaMine-D3 hydrochloride KetaMine-D3 hydrochloride 1073254-49-5 C13H17Cl2NO
Sulfaphenazole-13C6 Sulfaphenazole-13C6 1420043-53-3 C15H14N4O2S
CDTA, 1,2-CyclohexanediaMinetetraacetic acis CDTA, 1,2-CyclohexanediaMinetetraacetic acis 145819-99-4 C14H24N2O9
Methyl viologen dichloride hydrate 98% Methyl viologen dichloride hydrate 98% 75365-73-0 C12H16Cl2N2O
4-(2-Ethyl-1-methylhexyl)phenol
		
	4-(2-Ethyl-1-methylhexyl)phenol 186825-39-8 C15H24O
1,3-Propanediyl-bis(tripropylphosphonium) difluoride solution
		
	1,3-Propanediyl-bis(tripropylphosphonium) difluoride solution 1204424-34-9 C21H48FP2+
1,5-Pentanediyl-bis(1-butylpyrrolidinium) difluoride solution
		
	1,5-Pentanediyl-bis(1-butylpyrrolidinium) difluoride solution 1245190-20-8 C21H44FN2+
Benzoylecgonine tetrahydrate
		
	Benzoylecgonine tetrahydrate 5928-96-1 C16H21NO5
Carbon Dioxide (1%) and Oxygen (20%) in Nitrogen
		
	Carbon Dioxide (1%) and Oxygen (20%) in Nitrogen CO2
tube racks tube racks
EPA TO-14A GC-MS Tuning Standard
		
	EPA TO-14A GC-MS Tuning Standard
ASTM D4815 Quantitative Calibration Mixture 1
		
	ASTM D4815 Quantitative Calibration Mixture 1
ASTM D4815 Quantitative Calibration Mixture 5
		
	ASTM D4815 Quantitative Calibration Mixture 5
ASTM D4815 Qualitative ID Mix
		
	ASTM D4815 Qualitative ID Mix
Isosorbide Solution
		
	Isosorbide Solution C6H10O4
ASTM D5441 MTBE Contaminants (high) Mix A
		
	ASTM D5441 MTBE Contaminants (high) Mix A
EPA 8240/8260 VOA Surrogate Spike Mix
		
	EPA 8240/8260 VOA Surrogate Spike Mix
Radiello Methylene Blue Calibration Standard for H2S (Hydrogen Sulfide)
		
	Radiello Methylene Blue Calibration Standard for H2S (Hydrogen Sulfide)
Spectroline CM UV-viewing cabinet
		
	Spectroline CM UV-viewing cabinet
Adsorbent scrapers
		
	Adsorbent scrapers
Preparative TLC plates
		
	Preparative TLC plates
Hellma absorption cuvettes, Micro
		
	Hellma absorption cuvettes, Micro
2,4,5-T-AMINE 2,4,5-T-AMINE C14H20Cl3NO3
MULTIELEMENT ICP-MS TUNING SOLUTION I MULTIELEMENT ICP-MS TUNING SOLUTION I
PENTANOIC-2-13C ACID PENTANOIC-2-13C ACID C5H10O2
ACROLEIN/ACRYLONITRILE MIX ACROLEIN/ACRYLONITRILE MIX C6H7NO
METHYL 10-METHYLOCTADECANOATE METHYL 10-METHYLOCTADECANOATE C20H40O2
4-METHYLPENTANOIC ACID-1-13C 4-METHYLPENTANOIC ACID-1-13C 286013-24-9 C6H12O2
BOEHMER'S SOLUTION BOEHMER'S SOLUTION
(+/-)-CIS-4,5-EPOXY-(7Z),14(Z),13(Z),16(Z),19(Z)-DOCOSAPENTAENOIC ACID METHYL ESTER (+/-)-CIS-4,5-EPOXY-(7Z),14(Z),13(Z),16(Z),19(Z)-DOCOSAPENTAENOIC ACID METHYL ESTER C22H32O3
CHOLESTEROL-3-OCTANOATE (OCTANOATE-1-13C) CHOLESTEROL-3-OCTANOATE (OCTANOATE-1-13C) C35H60O2
(+/-)-N-HYDROXY-3 4-METHYLENEDIOXYAMPHE& (+/-)-N-HYDROXY-3 4-METHYLENEDIOXYAMPHE& 114562-59-3 C10H13NO3
CALCIUM IONOPHORE VI CALCIUM IONOPHORE VI 171979-66-1 C100H108O8P4
HEXADECANOIC-16,16,16-D3 ACID HEXADECANOIC-16,16,16-D3 ACID 75736-53-7 CD3(CH2)14COOH
BUFFER SOLUTION PH 3.0 (20 C) BUFFER SOLUTION PH 3.0 (20 C)
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