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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
4-tert-Octylphenyl-3,5-D2 Monoethoxylate Solution, 1ug/ml in Acetone 4-tert-Octylphenyl-3,5-D2 Monoethoxylate Solution, 1ug/ml in Acetone 1173022-57-5 C16H24D2O2
Nabam-d4 hexahydrate Nabam-d4 hexahydrate
4,5-Dihydroxy-2,2-bis(3-methyl-2-butenyl)- 4-cyclopentene-1,3-dione 4,5-Dihydroxy-2,2-bis(3-methyl-2-butenyl)- 4-cyclopentene-1,3-dione 1891-42-5 C15H20O4
Dimethachlor Metabolite CGA 373464
		
	Dimethachlor Metabolite CGA 373464 1196157-87-5 C12H16NNaO6S
Salbutamol acetate Salbutamol acetate 1420043-41-9 C15H25NO5
S-Metolachlor Metabolite NOA 413173
		
	S-Metolachlor Metabolite NOA 413173 1418095-19-8 C14H19NO6S
Salicylate ionophore II
		
	Salicylate ionophore II 1005344-82-0 C33H69N7S3
5-(Nonadecyl-1,1,2,2-d4)resorcinol
		
	5-(Nonadecyl-1,1,2,2-d4)resorcinol 1108148-95-3 C25H40D4O2
Tin(II) ionophore II
		
	Tin(II) ionophore II 13591-58-7 C22H17N3O2
Albendazole sulfoxide-D3
Ricobendazole-D3 Albendazole sulfoxide-D3 Ricobendazole-D3 1448346-38-0 C12H12D3N3O3S
Cyclopentylalbendazole sulfoxide Cyclopentylalbendazole sulfoxide 131454-43-8 C14H17N3O3S
Hydroxytriclabendazole Hydroxytriclabendazole 109536-21-2 C14H9Cl3N2O2S
Sulfachloropyrazine-13C6 Sulfachloropyrazine-13C6 1416711-61-9
Sulfanitran-13C6 Sulfanitran-13C6 1353867-79-4 C14H13N3O5S
Mycophenolic acid-<sup>13</sup>C<sub>17</sub> Mycophenolic acid-13C17 1202866-92-9 C17H20O6
ASTM D4815 Quantitative Calibration Mixture 2
		
	ASTM D4815 Quantitative Calibration Mixture 2
Sigma Pseudo Narcotic Scent Marijuana formulation
		
	Sigma Pseudo Narcotic Scent Marijuana formulation
EPA OLM04 Pesticide Standard Mix A-1
		
	EPA OLM04 Pesticide Standard Mix A-1
Bacitracin F, 1-[N-[[2-(1-amino-2-methylbutyl)-4,5-dihydro-4-thiazolyl]carbonyl]-l-leucine]- Bacitracin F, 1-[N-[[2-(1-amino-2-methylbutyl)-4,5-dihydro-4-thiazolyl]carbonyl]-l-leucine]- 22601-59-8 C66H103N17O16S
1-(3,4-dichlorophenyl)-5-isopropylbiguanide monohydrochloride 1-(3,4-dichlorophenyl)-5-isopropylbiguanide monohydrochloride 6001-93-0 C11H16Cl3N5
POLYGLYCERYL-3 DIISOSTEARATE POLYGLYCERYL-3 DIISOSTEARATE 66082-42-6 C45H88O9
BRUSSEL SPROUT - VITAMINS(CRM STANDARD) BRUSSEL SPROUT - VITAMINS(CRM STANDARD)
ALKALI BLUE SOLUTION ALKALI BLUE SOLUTION
C8 SILICA GEL C8 SILICA GEL
POLYETHYLENIMINE ON SILICA GEL POLYETHYLENIMINE ON SILICA GEL
Phospray
		
	Phospray
DL-3-HYDROXYTETRADECANOIC ACID-2,2,3,4,4-D5 DL-3-HYDROXYTETRADECANOIC ACID-2,2,3,4,4-D5 284487-60-1 C14H28O3
134-84-9 134-84-9 134-84-9
Oxymetazoline impurity A Oxymetazoline impurity A
AMMonia as N IC standard AMMonia as N IC standard
Amino acids standard
		
	Amino acids standard
Triprolidine Hydrochloride Z-IsoMer Triprolidine Hydrochloride Z-IsoMer 51657-91-1 C19H23ClN2
(±)-Epinephrine-D6 (±)-Epinephrine-D6 1219803-77-6 C9H13NO3
GMO MAIZE POWDER STANDARD MON 863 GMO MAIZE POWDER STANDARD MON 863
67-43-6 67-43-6 67-43-6
FLUORESCENT IEF MARKER PI 4.5 FLUORESCENT IEF MARKER PI 4.5
FlufenaMic acid-13C6 FlufenaMic acid-13C6 1325559-30-5 C14H10F3NO2
Oxyclosanid-13C6 Oxyclosanid-13C6 1353867-74-9 C13H6Cl5NO3
Methyl linolenate (C18:3n6) Methyl linolenate (C18:3n6)
HYDROXYBUFURALOL MALEATE HYDROXYBUFURALOL MALEATE C20H27NO7
EPA VOA Matrix Spike Mix
		
	EPA VOA Matrix Spike Mix
EPA 8010 Halogenated VOC Mix 1
		
	EPA 8010 Halogenated VOC Mix 1
EPA OLMO4 Pesticide Standard Mix A
		
	EPA OLMO4 Pesticide Standard Mix A
Aldrich rectangular TLC developing tanks, lid only
		
	Aldrich rectangular TLC developing tanks, lid only
TLC saturation pads
		
	TLC saturation pads
TLC Glass Plates from EMD/Merck KGaA
		
	TLC Glass Plates from EMD/Merck KGaA
Hellma absorption cuvettes, ultra Micro
		
	Hellma absorption cuvettes, ultra Micro
Aldrich cuvette washer and drier
		
	Aldrich cuvette washer and drier
Hellma calibration standards, Complete Glass Filter Set: F1, F2, F3, F4, F0
		
	Hellma calibration standards, Complete Glass Filter Set: F1, F2, F3, F4, F0
Replacement nuts for Aldrich adjustable cell holder
		
	Replacement nuts for Aldrich adjustable cell holder
Adapter for agate vial for analog Wig-L-Bug grinder/mixer
		
	Adapter for agate vial for analog Wig-L-Bug grinder/mixer
Lanthanum Standard for ICP
		
	Lanthanum Standard for ICP La
Nonylphenol diethoxylate solution
		
	Nonylphenol diethoxylate solution
Buffer solution pH 2.06 (20°C)
		
	Buffer solution pH 2.06 (20°C)
CYANOAQUA-COBYRINIC ACID HEPTAKIS(2-PHENYLETHYL ESTER) CYANOAQUA-COBYRINIC ACID HEPTAKIS(2-PHENYLETHYL ESTER) 130549-56-3 C102H117ClCoN5O19
POTASSIUM IONOPHORE I - COCKTAIL A POTASSIUM IONOPHORE I - COCKTAIL A
5(E),8(Z),11(Z),14(Z)-Eicosatetraenoicacid(5(E)-Arachidonic)MethylEster 5(E),8(Z),11(Z),14(Z)-Eicosatetraenoicacid(5(E)-Arachidonic)MethylEster
Methyl9c,11c-Octadecadienoate Methyl9c,11c-Octadecadienoate
MethylDocosadienoate(13c,16c) MethylDocosadienoate(13c,16c)
MethylPetroselinoate(6c) MethylPetroselinoate(6c)
3-[bis(2-ethylhexyl)phosphorylmethyl]heptane 3-[bis(2-ethylhexyl)phosphorylmethyl]heptane 2785-32-2 C24H51OP
2',3'-dideoxycytidine 5'-triphosphate 2',3'-dideoxycytidine 5'-triphosphate 66004-77-1 C9H16N3O12P3
NO1FUELOIL NO1FUELOIL
1,1,1-TRICHLOROETHANE (2,2,2-D3, 98%) 1,1,1-TRICHLOROETHANE (2,2,2-D3, 98%) C2Cl3D3
BARIUM IONOPHORE I BARIUM IONOPHORE I 96476-01-6 C40H56N2O5
2R-EPHEDRONE HYDROCHLORIDE 2R-EPHEDRONE HYDROCHLORIDE 152610-69-0 C10H14ClNO
MICRO PARTICLES BASED ON POLYSTYRENE MICRO PARTICLES BASED ON POLYSTYRENE
Calcium, AAS standard solution, Specpure, Ca 1000μg/ml Calcium, AAS standard solution, Specpure, Ca 1000μg/ml Ca
Platinum, AAS standard solution, Specpure, Pt 1000μg/ml Platinum, AAS standard solution, Specpure, Pt 1000μg/ml Pt
GMO  Standard  ERM-BF415,  Maize  NK603 GMO Standard ERM-BF415, Maize NK603
GMO  Standard  ERM-BF414,  Maize  GA21 GMO Standard ERM-BF414, Maize GA21
Underground  Storage  Tank  (UST)  Modified  GRO Underground Storage Tank (UST) Modified GRO
EPA  624  Purgeables  Kit EPA 624 Purgeables Kit
Methyl-13C,d1  iodide Methyl-13C,d1 iodide 55487-75-7 CH3I
EPA  8270  Herbicide  Ester  Mix EPA 8270 Herbicide Ester Mix
Rhodium  Standard  for  ICP Rhodium Standard for ICP Rh
ATR/MIR  crystal  prism ATR/MIR crystal prism
EPA  HC  Purgeable  B EPA HC Purgeable B
EPA  8011  EDB/DBCP  Mix EPA 8011 EDB/DBCP Mix
Milk  powder  (PCDDs,  PCDFs) Milk powder (PCDDs, PCDFs)
EPA  8260  Surrogate  Standards  Mix  2 EPA 8260 Surrogate Standards Mix 2
EPA  8020B  Aromatic  Volatile  Organics  Mix  1 EPA 8020B Aromatic Volatile Organics Mix 1
Polymer  kit,  acrylate  secondary  standards Polymer kit, acrylate secondary standards
Bovine  urine  (hexoestrol  positive) Bovine urine (hexoestrol positive)
Glass-ceramic  (thermal  conductivity  and  diffusivity) Glass-ceramic (thermal conductivity and diffusivity)
EPA  8080/8270  Pesticide  Surrogate  Mix EPA 8080/8270 Pesticide Surrogate Mix
KDWR  Pesticides  Kit KDWR Pesticides Kit
EPA  TCL  Calibration  Standards  Kit EPA TCL Calibration Standards Kit
Carbon  Monoxide  (5%),  Carbon  Dioxide  (5%),  Nitrogen  (5%),  Oxygen  (5%),  Methane  (4%)  and  Hydrogen  (4%) Carbon Monoxide (5%), Carbon Dioxide (5%), Nitrogen (5%), Oxygen (5%), Methane (4%) and Hydrogen (4%) CH2O
Silicon  (isotope  ratio) Silicon (isotope ratio)
2,4-Dinitrophenylhydrazones,  solutions,  set 2,4-Dinitrophenylhydrazones, solutions, set
Coastal  sea  water  (Hg) Coastal sea water (Hg)
n-Paraffin  Mix  C10,C12,C14,C16 n-Paraffin Mix C10,C12,C14,C16
Nitrogen  in  helium Nitrogen in helium
Spectra  Catalogue Spectra Catalogue
EPA  CLP  Volatiles  Calibration  Mix  A EPA CLP Volatiles Calibration Mix A
EPA  625  Semivolatile  Calibration  Mix EPA 625 Semivolatile Calibration Mix
EPA  Acid  Calibration  Mix  1 EPA Acid Calibration Mix 1
Nickel  ICP/DCP  standard  solution Nickel ICP/DCP standard solution Ni
Quebec  Phenol  MIx Quebec Phenol MIx
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