一般描述
(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions.
應(yīng)用
(S)-QUINAP can be used as a ligand: In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)2.?????? For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.
Sigma-Aldrich西格瑪奧德里奇(上海)貿(mào)易有限公司
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