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Tetrahedron Letters

Tetrahedron Letters

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Alkaloid induced asymmetric electrocarboxylation of 4-methylpropiophenone

Published:25 May 2011 DOI: 10.1016/j.tetlet.2011.03.076
Shu-Feng Zhao, Mei-Xia Zhu, Kai Zhang, Huan Wang, Jia-Xing Lu

Abstract

The alkaloid-induced electrocarboxylation of 4-methylpropiophenone is examined in mild conditions. Comparative studies with several inductors indicate that the efficient enantiodiscrimination of the electrocarboxylation depends on the nucleophilic quinuclidine nitrogen atom and the OH group of the inductors.

Substances (2)

Related products
Procduct Name CAS Molecular Formula Supplier Price
4'-Methylpropiophenone 5337-93-9 C10H12O 539 suppliers $10.00-$2340.72
QUINUCLIDINE 100-76-5 C7H13N 192 suppliers $4.00-$4389.00

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