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Chemical Communications

Chemical Communications

IF: 4.3
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First successful reaction of a silyl anion with hafnium tetrachloride

Published:30 April 2002 DOI: 10.1039/B201508K PMID: 12109076
Dieter Frank, Judith Baumgartner and Christoph Marschner

Abstract

Hafnium tetrachloride reacts with the tris(trimethylsilyl)silyl potassium tmen adduct (1) to form a [tris(trimethylsilyl)silyl]trichlorohafnium tmen complex (2); reaction of 2 with 2,6-dimethylphenylisonitrile leads to insertion into the silicon hafnium bond (4).

Substances (3)

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Procduct Name CAS Molecular Formula Supplier Price
Hafnium(IV) chloride 13499-05-3 Cl4Hf 227 suppliers $22.30-$1618.00
2,6-DIMETHYLPHENYL ISOCYANIDE 2769-71-3 C9H9N 107 suppliers $26.00-$2809.00
TRIS(TRIMETHYLSILOXY)CHLOROSILANE 17905-99-6 C9H27ClO3Si4 52 suppliers $148.05-$148.05

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