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Journal of Chemical Research-s

Journal of Chemical Research-s

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Efficient Three-Component Strecker Reaction of Acetals and Aromatic Amines Catalysed by Hafnium Tetrachloride at Room Temperature

Published:1 November 2013 DOI: 10.3184/174751913X13814077309487
Xuelin Zhang,?Qin-pei Wu,?Qingshan Zhang

Abstract

A straightforward, mild, efficient, one-pot method has been found for the synthesis of α-aminonitriles via three-component Strecker reaction using acetals or cyclic acetals, curious aromatic amines and trimethylsilyl cyanide (TMSCN) catalysed by hafnium tetrachloride at room temperature. It is with good to excellent yields under mild conditions. This developed approach has been successfully applied for the synthesis of a wild rang of α-aminonitriles with a variety of functional groups.

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Related products
Procduct Name CAS Molecular Formula Supplier Price
Trimethylsilyl cyanide 7677-24-9 C4H9NSi 480 suppliers $19.00-$1873.00
Hafnium(IV) chloride 13499-05-3 Cl4Hf 225 suppliers $22.30-$1618.00
5-BROMO-2-CHLOROBENZALDEHYDE C7H4BrClO 21 suppliers Inquiry
4-OCTYLBENZYLAMINE 176956-02-8 C15H25N 14 suppliers Inquiry

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