1,3-Dichlorobenzene synthesis
- Product Name:1,3-Dichlorobenzene
- CAS Number:541-73-1
- Molecular formula:C6H4Cl2
- Molecular Weight:147
Add o-chloroaniline and hydrochloric acid into the reaction pot, mix evenly below 25°C, cool to 0°C, drop in sodium nitrite solution, control the temperature at 0-5°C, stop adding when the potassium iodide starch indicator turns blue, and obtain diazonium salt solution. Then add the diazonium salt solution into the hydrochloric acid solution of cuprous chloride at 0～5℃, stir well, heat up to 60～70℃ and react for 1h, after cooling, let stand for stratification, and use 5% sodium hydroxide for the oil layer. Repeated washing with water, dehydration with anhydrous calcium chloride, fractional distillation, and collection of fractions at 177-183 °C to obtain the product 1,3-dichlorobenzene.
121-73-3
72 suppliers
$10.00/1g
541-73-1
406 suppliers
$22.00/25G
Yield:541-73-1 474.6 kg
Reaction Conditions:
with chlorine at 190;Large scale;Temperature;
Steps:
1.3; 2.3; 3.3; 4.3
517kg m-chloronitrobenzene and 116kg chlorine gas are continuously put into the tower and then heated to 190°C, meanwhile m-dichlorobenzene and tail gas are continuously distilled out,The tail gas enters the dilute nitric acid tower and is used for nitrification in the next section.Then, distill off the m-dichlorobenzene that has been distilled off and collect it for distillation.474.6kg of dichlorobenzene between finished products;
References:
CN111153779,2020,A Location in patent:Paragraph 0026; 0030; 0036; 0040; 0046; 0050; 0056; 0060
50-30-6
368 suppliers
$5.00/5g
541-73-1
406 suppliers
$22.00/25G
50-84-0
490 suppliers
$9.00/1g
541-73-1
406 suppliers
$22.00/25G
87-61-6
225 suppliers
$14.00/25g
108-90-7
690 suppliers
$10.00/25G
95-50-1
597 suppliers
$10.00/5g
541-73-1
406 suppliers
$22.00/25G
71-43-2
719 suppliers
$11.19/25ML
99-65-0
25 suppliers
$32.00/25g
541-73-1
406 suppliers
$22.00/25G