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ChemicalBook CAS DataBase List 1-PENTADECENE
13360-61-7

1-PENTADECENE synthesis

11synthesis methods
To a 10 mL Schlenk reaction tube (F891410 reaction tube, 10 mL capacity, mill 14/20) was added the photocatalyst palladium chloride (2 mol%, 0.7 mg), 4,5-bis(diphenylphosphino)-9,9-dimethyloxanthene (L1) (3 mol%, 3.5 mg), 2-(dicyclohexylphosphino)biphenyl
-

Yield:13360-61-7 95 %Chromat.

Reaction Conditions:

Stage #1: pentadec-1-ynewith tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane at 20; for 0.25 h;Inert atmosphere;
Stage #2: with formic acid in 1,4-dioxane at 80; for 3 h;Inert atmosphere;

References:

Shen, Ruwei;Chen, Tieqiao;Zhao, Yalei;Qiu, Renhua;Zhou, Yongbo;Yin, Shuangfeng;Wang, Xiangbo;Goto, Midori;Han, Li-Biao [Journal of the American Chemical Society,2011,vol. 133,# 42,p. 17037 - 17044] Location in patent:supporting information; experimental part

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