3,3',5,5'-TETRA(TERT-BUTYL)[1,1'-BIPHENYL]-4,4'-DIOL synthesis
- Product Name:3,3',5,5'-TETRA(TERT-BUTYL)[1,1'-BIPHENYL]-4,4'-DIOL
- CAS Number:128-38-1
- Molecular formula:C28H42O2
- Molecular Weight:410.63
732-26-3
214 suppliers
$40.00/25g
128-38-1
71 suppliers
$42.00/200mg
Yield:-
Reaction Conditions:
with [FeIV (N,N-bis(2-pyridylmethyl)-1,2-di(2-pyridyl)ethylamine)(O)](ClO4)2 in acetonitrile at 24.84;Kinetics;Inert atmosphere;
Steps:
2.2 Stoichiometric oxidations
General procedure: [FeII (asN4Py)(CH3CN)](ClO4)2 complex (2.00×10-3M) was dissolved in acetonitrile (1.5mL), then iodosobenzene (2.4×10-3M) was added to the solution. The mixture was stirred for 40min then excess iodosobenzene was removed by filtration. Substrate (1.00×10-2-4.00×10-2M) was added to the solution and the reaction was monitored with UV-vis spectrophotometer at 705nm (ε=400M-1cm-1) (Table 1 ). The characterization of the product 4,4′-dihydroxy-3,3′,5,5′-tetra-tert-butylbiphenyl (H2DPQ) based on previously described methods [6c].
References:
Lakk-Bogáth, Dóra;Speier, Gábor;Kaizer, József [Polyhedron,2018,vol. 145,p. 227 - 230]
128-39-2
358 suppliers
$5.00/25g
128-38-1
71 suppliers
$42.00/200mg
2455-14-3
139 suppliers
$6.00/1g
128-38-1
71 suppliers
$42.00/200mg
732-26-3
214 suppliers
$40.00/25g
719-22-2
189 suppliers
$14.00/5g
2455-14-3
139 suppliers
$6.00/1g
128-38-1
71 suppliers
$42.00/200mg
128-39-2
358 suppliers
$5.00/25g
2455-14-3
139 suppliers
$6.00/1g
128-38-1
71 suppliers
$42.00/200mg