4-Methoxyphenylacetone synthesis
- Product Name:4-Methoxyphenylacetone
- CAS Number:122-84-9
- Molecular formula:C10H12O2
- Molecular Weight:164.2
104-46-1
360 suppliers
$5.00/100mg
122-84-9
482 suppliers
$5.00/5g
Yield:122-84-9 85 %Spectr.
Reaction Conditions:
with [Ru(2,6-Cl2tpp)Cl2];2,6-dichloropyridine N-oxide in chloroform-d1 at 60; for 2 h;Wacker Oxidation;
Steps:
Alkene substrate (0.1 mmol) and internal standard compound trimethylphenylsilicane(5 μL) were dissolved in CDCl3 (0.5 ml) in an NMR tube to record a 1H NMR. Then[RuIV(TDCPP)Cl2] (2.0 mol%) and Cl2pyNO (1.03 equiv) were added and kept themixture at 60 oC. The progress of the reaction was monitored by 1H NMR. Afterdetermination of the product yield by 1H NMR spectroscopy, the product ketone wasseparated by flash chromatography on silica gel.
References:
Wang, Zhi-Ming;Sang, Xue-Ling;Che, Chi-Ming;Chen, Jian [Tetrahedron Letters,2014,vol. 55,# 10,p. 1736 - 1739] Location in patent:supporting information
1712-69-2
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$45.00/5mg
122-84-9
482 suppliers
$5.00/5g
140-67-0
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$12.00/25g
122-84-9
482 suppliers
$5.00/5g
17354-63-1
12 suppliers
$99.70/1g
122-84-9
482 suppliers
$5.00/5g
