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ChemicalBook CAS DataBase List Chromium hexacarbonyl
13007-92-6

Chromium hexacarbonyl synthesis

5synthesis methods
Chromium hexacarbonyl is prepared by the reaction of anhydrous chromium(III) chloride with carbon monoxide in the presence of a Grignard reagent. A 60% product yield may be obtained at the carbon monoxide pressures of 35 to 70 atm. Other chromium salts may be used with carbon monoxide and Grignard reagent in the preparation. The compound may also be obtained by the reaction of a chromium salt with carbon monoxide in the presence of magnesium in ether or sodium in diglyme.
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Yield:105394-78-3 100%

Reaction Conditions:

with methanol in methanol;Irradiation (UV/VIS); solid carbene complex in dry methanol is added to an oven-dried Pyrex pressure tube, contents are degassed, purged with Ar, warmed to room temp., purged with CO, pressurized with 50-90 psi CO, irradiated (450 W) for 5 d; monitored by TLC, mixt. is filtered (Celite) to remove solid Cr(CO)6, evapn. in vacuo, air oxidn. overnight, filtn.; NMR, IR, elem. anal.;

References:

Hegedus, Louis S.;Schwindt, Mark A.;De Lombaert, Stéphane;Imwinkelried, Rene [Journal of the American Chemical Society,1990,vol. 112,# 6,p. 2264 - 2273]

201230-82-2 Synthesis
carbon monoxide

201230-82-2
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10025-73-7 Synthesis
Chromium(III) chloride

10025-73-7
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$22.39/5G

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