Decane synthesis
- Product Name:Decane
- CAS Number:124-18-5
- Molecular formula:C10H22
- Molecular Weight:142.28
1942-46-7
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124-18-5
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$24.00/25mL
Yield:124-18-5 96 %Chromat.
Reaction Conditions:
with C5H14NO(1+)*C10H12NO4S(1-)*Pd;hydrogen in glycerol at 80; under 2250.23 Torr; for 2 h;Inert atmosphere;Schlenk technique;
Steps:
2.5. General procedure for Pd-catalyzed hydrogenation in glycerol
General procedure: In a Fisher-Porter bottle (working from 1 to 3 bar total pressure) oran autoclave (working from 3 to 20 bar total pressure), the appropriate substrate (1 mmol for 1 mol % of catalyst or 10 mmol for 0.1 mol% of catalyst) was added to 1 mL of preformed nanoparticles (2.85 mg of Pd) in glycerol under argon. The reaction mixture was put under vacuum and then pressurized with H2 at the convenient pressure, heated up at 80 °C and stirred for the appropriate time; then cooled down to room temperature before extraction. Organic products were extracted from glycerol by a biphasic methodology, adding dichloromethane (5×3 mL); organic phases were collected and solvent removed under vacuum. Conversion and yields were determined by GC using decane as internal standard. The obtained products were characterized by GC-MS data and 1H and 13C NMR and compared to literature reports to confirm spectral identity (see Supplementary Material).
References:
Garg, Garima;Foltran, Stéphanie;Favier, Isabelle;Pla, Daniel;Medina-González, Yaocihuatl;Gómez, Montserrat [Catalysis Today,2020,vol. 346,p. 69 - 75]
2050-77-3
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124-18-5
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872-05-9
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124-18-5
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142-62-1
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124-18-5
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17490-66-3
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124-18-5
259 suppliers
$24.00/25mL