Formic acid synthesis
- Product Name:Formic acid
- CAS Number:64-18-6
- Molecular formula:CH2O2
- Molecular Weight:46.03
56-81-5
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64-18-6
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Yield:64-18-6 99%
Reaction Conditions:
with CeO2#CuO;oxygen in lithium hydroxide monohydrate at 120; under 4500.45 Torr; for 10 h;Irradiation;Temperature;Pressure;Reagent/catalyst;
Steps:
1-29; 37-41 Example 8
Disperse 10mmol glycerol and 50mg 1mol% CuO/CeO2 in 25mL water, add magnet, replace with oxygen three times and keep the pressure at 0.6Mpa, irradiate the reaction with visible light of 200mW/cm2 wavelength of 455nm at 120 for 10h,After the reaction was completed, it was quantified by HPLC, the conversion rate of glycerol was 100%, and the yield of formic acid was 99%.
References:
CN113024370,2021,A Location in patent:Paragraph 0023-0024; 0025-0026; 0027-0028; 0029-0030; ...
56-82-6
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64-18-6
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64-18-6
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79-14-1
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64-18-6
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